Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions

High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.

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Autores principales:	Simon D. Kloß, Arthur Haffner, Pascal Manuel, Masato Goto, Yuichi Shimakawa, J. Paul Attfield
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d9671dfd9f124e13884e329a3f5ad3b2
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spelling	oai:doaj.org-article:d9671dfd9f124e13884e329a3f5ad3b22021-12-02T13:57:43ZPreparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions10.1038/s41467-020-20881-y2041-1723https://doaj.org/article/d9671dfd9f124e13884e329a3f5ad3b22021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20881-yhttps://doaj.org/toc/2041-1723High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.Simon D. KloßArthur HaffnerPascal ManuelMasato GotoYuichi ShimakawaJ. Paul AttfieldNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-6 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Simon D. Kloß Arthur Haffner Pascal Manuel Masato Goto Yuichi Shimakawa J. Paul Attfield Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
description	High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.
format	article
author	Simon D. Kloß Arthur Haffner Pascal Manuel Masato Goto Yuichi Shimakawa J. Paul Attfield
author_facet	Simon D. Kloß Arthur Haffner Pascal Manuel Masato Goto Yuichi Shimakawa J. Paul Attfield
author_sort	Simon D. Kloß
title	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_short	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_full	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_fullStr	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_full_unstemmed	Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions
title_sort	preparation of iron(iv) nitridoferrate ca4fen4 through azide-mediated oxidation under high-pressure conditions
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d9671dfd9f124e13884e329a3f5ad3b2
work_keys_str_mv	AT simondkloß preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT arthurhaffner preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT pascalmanuel preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT masatogoto preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT yuichishimakawa preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions AT jpaulattfield preparationofironivnitridoferrateca4fen4throughazidemediatedoxidationunderhighpressureconditions
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Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions

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