Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions

Preparation of iron(IV) nitridoferrate Ca4FeN4 through azide-mediated oxidation under high-pressure conditions

High-valent metal nitrides are difficult to stabilise due to the high thermodynamic stability and chemical inertness of N2. Here, the authors employ a large volume press to prepare an iron(IV) nitridoferrate Ca4FeIVN4 from Fe2N and Ca3N2 via azide-mediated oxidation under high pressure conditions.

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Autores principales: Simon D. Kloß, Arthur Haffner, Pascal Manuel, Masato Goto, Yuichi Shimakawa, J. Paul Attfield
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Science
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Acceso en línea:https://doaj.org/article/d9671dfd9f124e13884e329a3f5ad3b2
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