Bis-silylation of internal alkynes enabled by Ni(0) catalysis

Bis-silylated alkenes offer the advantage of two functional handles with distinguished reactivity for downstream functionalization. Here, the authors report a nickel-catalyzed bis-silylation of internal alkynes to versatile silylated alkene intermediates which can be chemoselectively manipulated.

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Detalles Bibliográficos
Autores principales:	Yun Zhang, Xi-Chao Wang, Cheng-Wei Ju, Dongbing Zhao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d98163b8a0ff4e948f20431981c2b554
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spelling	oai:doaj.org-article:d98163b8a0ff4e948f20431981c2b5542021-12-02T15:16:23ZBis-silylation of internal alkynes enabled by Ni(0) catalysis10.1038/s41467-020-20392-w2041-1723https://doaj.org/article/d98163b8a0ff4e948f20431981c2b5542021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20392-whttps://doaj.org/toc/2041-1723Bis-silylated alkenes offer the advantage of two functional handles with distinguished reactivity for downstream functionalization. Here, the authors report a nickel-catalyzed bis-silylation of internal alkynes to versatile silylated alkene intermediates which can be chemoselectively manipulated.Yun ZhangXi-Chao WangCheng-Wei JuDongbing ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yun Zhang Xi-Chao Wang Cheng-Wei Ju Dongbing Zhao Bis-silylation of internal alkynes enabled by Ni(0) catalysis
description	Bis-silylated alkenes offer the advantage of two functional handles with distinguished reactivity for downstream functionalization. Here, the authors report a nickel-catalyzed bis-silylation of internal alkynes to versatile silylated alkene intermediates which can be chemoselectively manipulated.
format	article
author	Yun Zhang Xi-Chao Wang Cheng-Wei Ju Dongbing Zhao
author_facet	Yun Zhang Xi-Chao Wang Cheng-Wei Ju Dongbing Zhao
author_sort	Yun Zhang
title	Bis-silylation of internal alkynes enabled by Ni(0) catalysis
title_short	Bis-silylation of internal alkynes enabled by Ni(0) catalysis
title_full	Bis-silylation of internal alkynes enabled by Ni(0) catalysis
title_fullStr	Bis-silylation of internal alkynes enabled by Ni(0) catalysis
title_full_unstemmed	Bis-silylation of internal alkynes enabled by Ni(0) catalysis
title_sort	bis-silylation of internal alkynes enabled by ni(0) catalysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/d98163b8a0ff4e948f20431981c2b554
work_keys_str_mv	AT yunzhang bissilylationofinternalalkynesenabledbyni0catalysis AT xichaowang bissilylationofinternalalkynesenabledbyni0catalysis AT chengweiju bissilylationofinternalalkynesenabledbyni0catalysis AT dongbingzhao bissilylationofinternalalkynesenabledbyni0catalysis
_version_	1718387478906273792

Bis-silylation of internal alkynes enabled by Ni(0) catalysis

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