Bis-silylation of internal alkynes enabled by Ni(0) catalysis

Bis-silylated alkenes offer the advantage of two functional handles with distinguished reactivity for downstream functionalization. Here, the authors report a nickel-catalyzed bis-silylation of internal alkynes to versatile silylated alkene intermediates which can be chemoselectively manipulated.

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Detalles Bibliográficos
Autores principales: Yun Zhang, Xi-Chao Wang, Cheng-Wei Ju, Dongbing Zhao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Q
Acceso en línea:https://doaj.org/article/d98163b8a0ff4e948f20431981c2b554
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