Pulsed electroconversion for highly selective enantiomer synthesis

Synthesis of chiral molecules mostly relies on asymmetric catalysis. Here, the authors developed a pulsed electrochemical method to convert a prochiral ketone into the corresponding chiral alcohols with very high enantioselectivity on chiral-imprinted mesoporous platinum.

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Autores principales: Chularat Wattanakit, Thittaya Yutthalekha, Sunpet Asssavapanumat, Veronique Lapeyre, Alexander Kuhn
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/d9de3101d9174a7a9db8148b11d5ebb6
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Sumario:Synthesis of chiral molecules mostly relies on asymmetric catalysis. Here, the authors developed a pulsed electrochemical method to convert a prochiral ketone into the corresponding chiral alcohols with very high enantioselectivity on chiral-imprinted mesoporous platinum.