Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy
There currently exists some debate as to exact mechanism of cation exchange in semiconductor nanocrystals, a crucial question regarding the fundamental materials chemistry of these systems. Here, the authors report a detailed investigation of the mechanism of cation exchange in nanocrystals, which u...
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Nature Portfolio
2021
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oai:doaj.org-article:da132ad0e78842e8bbf024e478f122412021-12-02T14:19:11ZMechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy10.1038/s41467-020-20712-02041-1723https://doaj.org/article/da132ad0e78842e8bbf024e478f122412021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20712-0https://doaj.org/toc/2041-1723There currently exists some debate as to exact mechanism of cation exchange in semiconductor nanocrystals, a crucial question regarding the fundamental materials chemistry of these systems. Here, the authors report a detailed investigation of the mechanism of cation exchange in nanocrystals, which unambiguously shows evidence of interstitial intermediates during the exchange process.Alex KhammangJoshua T. WrightRobert W. MeulenbergNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021) |
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Science Q Alex Khammang Joshua T. Wright Robert W. Meulenberg Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy |
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There currently exists some debate as to exact mechanism of cation exchange in semiconductor nanocrystals, a crucial question regarding the fundamental materials chemistry of these systems. Here, the authors report a detailed investigation of the mechanism of cation exchange in nanocrystals, which unambiguously shows evidence of interstitial intermediates during the exchange process. |
format |
article |
author |
Alex Khammang Joshua T. Wright Robert W. Meulenberg |
author_facet |
Alex Khammang Joshua T. Wright Robert W. Meulenberg |
author_sort |
Alex Khammang |
title |
Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy |
title_short |
Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy |
title_full |
Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy |
title_fullStr |
Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy |
title_full_unstemmed |
Mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using X-ray absorption spectroscopy |
title_sort |
mechanistic insight into copper cation exchange in cadmium selenide semiconductor nanocrystals using x-ray absorption spectroscopy |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/da132ad0e78842e8bbf024e478f12241 |
work_keys_str_mv |
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_version_ |
1718391637416083456 |