Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels
The electrochemical reduction of carbon dioxide (CO<sub>2</sub>ER) is amongst one the most promising technologies to reduce greenhouse gas emissions since carbon dioxide (CO<sub>2</sub>) can be converted to value-added products. Moreover, the possibility of using a renewable...
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2021
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oai:doaj.org-article:da9ae5ed4e2b4797a4c94095ee56e27a2021-11-25T18:28:45ZElucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels10.3390/molecules262269621420-3049https://doaj.org/article/da9ae5ed4e2b4797a4c94095ee56e27a2021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6962https://doaj.org/toc/1420-3049The electrochemical reduction of carbon dioxide (CO<sub>2</sub>ER) is amongst one the most promising technologies to reduce greenhouse gas emissions since carbon dioxide (CO<sub>2</sub>) can be converted to value-added products. Moreover, the possibility of using a renewable source of energy makes this process environmentally compelling. CO<sub>2</sub>ER in ionic liquids (ILs) has recently attracted attention due to its unique properties in reducing overpotential and raising faradaic efficiency. The current literature on CO<sub>2</sub>ER mainly reports on the effect of structures, physical and chemical interactions, acidity, and the electrode–electrolyte interface region on the reaction mechanism. However, in this work, new insights are presented for the CO<sub>2</sub>ER reaction mechanism that are based on the molecular interactions of the ILs and their physicochemical properties. This new insight will open possibilities for the utilization of new types of ionic liquids. Additionally, the roles of anions, cations, and the electrodes in the CO<sub>2</sub>ER reactions are also reviewed.Sulafa Abdalmageed Saadaldeen MohammedWan Zaireen Nisa YahyaMohamad Azmi BustamMd Golam KibriaMDPI AGarticleionic liquidsCO<sub>2</sub> electrochemical reductionelectrolyteco-catalystOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6962, p 6962 (2021) |
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DOAJ |
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ionic liquids CO<sub>2</sub> electrochemical reduction electrolyte co-catalyst Organic chemistry QD241-441 |
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ionic liquids CO<sub>2</sub> electrochemical reduction electrolyte co-catalyst Organic chemistry QD241-441 Sulafa Abdalmageed Saadaldeen Mohammed Wan Zaireen Nisa Yahya Mohamad Azmi Bustam Md Golam Kibria Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels |
| description |
The electrochemical reduction of carbon dioxide (CO<sub>2</sub>ER) is amongst one the most promising technologies to reduce greenhouse gas emissions since carbon dioxide (CO<sub>2</sub>) can be converted to value-added products. Moreover, the possibility of using a renewable source of energy makes this process environmentally compelling. CO<sub>2</sub>ER in ionic liquids (ILs) has recently attracted attention due to its unique properties in reducing overpotential and raising faradaic efficiency. The current literature on CO<sub>2</sub>ER mainly reports on the effect of structures, physical and chemical interactions, acidity, and the electrode–electrolyte interface region on the reaction mechanism. However, in this work, new insights are presented for the CO<sub>2</sub>ER reaction mechanism that are based on the molecular interactions of the ILs and their physicochemical properties. This new insight will open possibilities for the utilization of new types of ionic liquids. Additionally, the roles of anions, cations, and the electrodes in the CO<sub>2</sub>ER reactions are also reviewed. |
| format |
article |
| author |
Sulafa Abdalmageed Saadaldeen Mohammed Wan Zaireen Nisa Yahya Mohamad Azmi Bustam Md Golam Kibria |
| author_facet |
Sulafa Abdalmageed Saadaldeen Mohammed Wan Zaireen Nisa Yahya Mohamad Azmi Bustam Md Golam Kibria |
| author_sort |
Sulafa Abdalmageed Saadaldeen Mohammed |
| title |
Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels |
| title_short |
Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels |
| title_full |
Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels |
| title_fullStr |
Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels |
| title_full_unstemmed |
Elucidation of the Roles of Ionic Liquid in CO<sub>2</sub> Electrochemical Reduction to Value-Added Chemicals and Fuels |
| title_sort |
elucidation of the roles of ionic liquid in co<sub>2</sub> electrochemical reduction to value-added chemicals and fuels |
| publisher |
MDPI AG |
| publishDate |
2021 |
| url |
https://doaj.org/article/da9ae5ed4e2b4797a4c94095ee56e27a |
| work_keys_str_mv |
AT sulafaabdalmageedsaadaldeenmohammed elucidationoftherolesofionicliquidincosub2subelectrochemicalreductiontovalueaddedchemicalsandfuels AT wanzaireennisayahya elucidationoftherolesofionicliquidincosub2subelectrochemicalreductiontovalueaddedchemicalsandfuels AT mohamadazmibustam elucidationoftherolesofionicliquidincosub2subelectrochemicalreductiontovalueaddedchemicalsandfuels AT mdgolamkibria elucidationoftherolesofionicliquidincosub2subelectrochemicalreductiontovalueaddedchemicalsandfuels |
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