MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions
Abstract Constructing the heterostructures is considered to be one of the most effective methods to improve the poor electrical conductivity and insufficient electrocatalytic properties of metal sulfide catalysts. In this work, MnCo2S4‐CoS1.097 nanotubes are successfully prepared via a reflux‐ hydro...
Guardado en:
| Autores principales: | , , , , , , , , , , |
|---|---|
| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Wiley
2021
|
| Materias: | |
| Acceso en línea: | https://doaj.org/article/daf815477d134724b1f5f898d540255c |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| id |
oai:doaj.org-article:daf815477d134724b1f5f898d540255c |
|---|---|
| record_format |
dspace |
| spelling |
oai:doaj.org-article:daf815477d134724b1f5f898d540255c2021-11-17T08:40:32ZMnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions2198-384410.1002/advs.202103302https://doaj.org/article/daf815477d134724b1f5f898d540255c2021-11-01T00:00:00Zhttps://doi.org/10.1002/advs.202103302https://doaj.org/toc/2198-3844Abstract Constructing the heterostructures is considered to be one of the most effective methods to improve the poor electrical conductivity and insufficient electrocatalytic properties of metal sulfide catalysts. In this work, MnCo2S4‐CoS1.097 nanotubes are successfully prepared via a reflux‐ hydrothermal process. This novel cathode catalyst delivers high discharge/charge specific capacities of 21 765/21 746 mAh g−1 at 200 mA g−1 and good rate capability. In addition, a favorable cycling stability with a fixed specific capacity of 1000 mAh g−1 at high current density of 1000 mA g−1 (167 cycles) and 2000 mA g−1 (57 cycles) are delivered. It is proposed that fast transmission of ions and electrons accelerated by the built‐in electric field, multiple active sites from the heterostructure, and nanotube architecture with large specific surface area are responsible for the superior electrochemical performance. To some extent, the rational design of this heterostructured metal sulfide catalyst provides guidance for the development of the stable and efficient cathode catalysts for Li‐O2 batteries that can be employed under high current conditions.Qing XiaLanling ZhaoZhijia ZhangJun WangDeyuan LiXue HanZhaorui ZhouYuxin LongFeng DangYiming ZhangShulei ChouWileyarticlecathode catalystselectrocatalysisheterostructureLi‐O2 batteriesMnCo2S4‐CoS1.097ScienceQENAdvanced Science, Vol 8, Iss 22, Pp n/a-n/a (2021) |
| institution |
DOAJ |
| collection |
DOAJ |
| language |
EN |
| topic |
cathode catalysts electrocatalysis heterostructure Li‐O2 batteries MnCo2S4‐CoS1.097 Science Q |
| spellingShingle |
cathode catalysts electrocatalysis heterostructure Li‐O2 batteries MnCo2S4‐CoS1.097 Science Q Qing Xia Lanling Zhao Zhijia Zhang Jun Wang Deyuan Li Xue Han Zhaorui Zhou Yuxin Long Feng Dang Yiming Zhang Shulei Chou MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions |
| description |
Abstract Constructing the heterostructures is considered to be one of the most effective methods to improve the poor electrical conductivity and insufficient electrocatalytic properties of metal sulfide catalysts. In this work, MnCo2S4‐CoS1.097 nanotubes are successfully prepared via a reflux‐ hydrothermal process. This novel cathode catalyst delivers high discharge/charge specific capacities of 21 765/21 746 mAh g−1 at 200 mA g−1 and good rate capability. In addition, a favorable cycling stability with a fixed specific capacity of 1000 mAh g−1 at high current density of 1000 mA g−1 (167 cycles) and 2000 mA g−1 (57 cycles) are delivered. It is proposed that fast transmission of ions and electrons accelerated by the built‐in electric field, multiple active sites from the heterostructure, and nanotube architecture with large specific surface area are responsible for the superior electrochemical performance. To some extent, the rational design of this heterostructured metal sulfide catalyst provides guidance for the development of the stable and efficient cathode catalysts for Li‐O2 batteries that can be employed under high current conditions. |
| format |
article |
| author |
Qing Xia Lanling Zhao Zhijia Zhang Jun Wang Deyuan Li Xue Han Zhaorui Zhou Yuxin Long Feng Dang Yiming Zhang Shulei Chou |
| author_facet |
Qing Xia Lanling Zhao Zhijia Zhang Jun Wang Deyuan Li Xue Han Zhaorui Zhou Yuxin Long Feng Dang Yiming Zhang Shulei Chou |
| author_sort |
Qing Xia |
| title |
MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions |
| title_short |
MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions |
| title_full |
MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions |
| title_fullStr |
MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions |
| title_full_unstemmed |
MnCo2S4‐CoS1.097 Heterostructure Nanotubes as High Efficiency Cathode Catalysts for Stable and Long‐Life Lithium‐Oxygen Batteries Under High Current Conditions |
| title_sort |
mnco2s4‐cos1.097 heterostructure nanotubes as high efficiency cathode catalysts for stable and long‐life lithium‐oxygen batteries under high current conditions |
| publisher |
Wiley |
| publishDate |
2021 |
| url |
https://doaj.org/article/daf815477d134724b1f5f898d540255c |
| work_keys_str_mv |
AT qingxia mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT lanlingzhao mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT zhijiazhang mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT junwang mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT deyuanli mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT xuehan mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT zhaoruizhou mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT yuxinlong mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT fengdang mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT yimingzhang mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions AT shuleichou mnco2s4cos1097heterostructurenanotubesashighefficiencycathodecatalystsforstableandlonglifelithiumoxygenbatteriesunderhighcurrentconditions |
| _version_ |
1718425704687730688 |