Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides

Thioesters are often suggested to be key intermediates in primordial metabolism, but prebiotic CO2 fixation routes to thioesters remain elusive. Here, the authors show nickel sulfide, partially reduced to Ni(0) with realistic geoelectric potentials, facilitates thioester (S-methyl thioacetate) forma...

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Autores principales:	Norio Kitadai, Ryuhei Nakamura, Masahiro Yamamoto, Satoshi Okada, Wataru Takahagi, Yuko Nakano, Yoshio Takahashi, Ken Takai, Yoshi Oono
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/db352959a66d4caca2bb3605fa05b9fb
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spelling	oai:doaj.org-article:db352959a66d4caca2bb3605fa05b9fb2021-12-02T17:05:48ZThioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides10.1038/s42004-021-00475-52399-3669https://doaj.org/article/db352959a66d4caca2bb3605fa05b9fb2021-03-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00475-5https://doaj.org/toc/2399-3669Thioesters are often suggested to be key intermediates in primordial metabolism, but prebiotic CO2 fixation routes to thioesters remain elusive. Here, the authors show nickel sulfide, partially reduced to Ni(0) with realistic geoelectric potentials, facilitates thioester (S-methyl thioacetate) formation via CO2-to-CO electroreduction, followed by a CO-methanethiol reaction.Norio KitadaiRyuhei NakamuraMasahiro YamamotoSatoshi OkadaWataru TakahagiYuko NakanoYoshio TakahashiKen TakaiYoshi OonoNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Norio Kitadai Ryuhei Nakamura Masahiro Yamamoto Satoshi Okada Wataru Takahagi Yuko Nakano Yoshio Takahashi Ken Takai Yoshi Oono Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides
description	Thioesters are often suggested to be key intermediates in primordial metabolism, but prebiotic CO2 fixation routes to thioesters remain elusive. Here, the authors show nickel sulfide, partially reduced to Ni(0) with realistic geoelectric potentials, facilitates thioester (S-methyl thioacetate) formation via CO2-to-CO electroreduction, followed by a CO-methanethiol reaction.
format	article
author	Norio Kitadai Ryuhei Nakamura Masahiro Yamamoto Satoshi Okada Wataru Takahagi Yuko Nakano Yoshio Takahashi Ken Takai Yoshi Oono
author_facet	Norio Kitadai Ryuhei Nakamura Masahiro Yamamoto Satoshi Okada Wataru Takahagi Yuko Nakano Yoshio Takahashi Ken Takai Yoshi Oono
author_sort	Norio Kitadai
title	Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides
title_short	Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides
title_full	Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides
title_fullStr	Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides
title_full_unstemmed	Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides
title_sort	thioester synthesis through geoelectrochemical co2 fixation on ni sulfides
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/db352959a66d4caca2bb3605fa05b9fb
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_version_	1718381820222898176

Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides

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