Thioester synthesis through geoelectrochemical CO2 fixation on Ni sulfides

Thioesters are often suggested to be key intermediates in primordial metabolism, but prebiotic CO2 fixation routes to thioesters remain elusive. Here, the authors show nickel sulfide, partially reduced to Ni(0) with realistic geoelectric potentials, facilitates thioester (S-methyl thioacetate) forma...

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Autores principales: Norio Kitadai, Ryuhei Nakamura, Masahiro Yamamoto, Satoshi Okada, Wataru Takahagi, Yuko Nakano, Yoshio Takahashi, Ken Takai, Yoshi Oono
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/db352959a66d4caca2bb3605fa05b9fb
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