Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method
Aluminum-doped zinc oxide thin films were deposited on glass substrates by the sol-gel technique. The effect of the Al concentration in the starting solution on the structural and optical properties of ZnO : Al thin films were studied. The molar ratio of the dopant (aluminum nitrate) in the solution...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2012
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oai:doaj.org-article:db5b83b4f86a4b2fb8d6482679158fdd2021-11-21T12:01:20ZAl-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method2537-63651810-648Xhttps://doaj.org/article/db5b83b4f86a4b2fb8d6482679158fdd2012-10-01T00:00:00Zhttps://mjps.nanotech.md/archive/2012/article/21316https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Aluminum-doped zinc oxide thin films were deposited on glass substrates by the sol-gel technique. The effect of the Al concentration in the starting solution on the structural and optical properties of ZnO : Al thin films were studied. The molar ratio of the dopant (aluminum nitrate) in the solution [Al/Zn] was varied between 1% and 3%.The deposition of the layers was realized performed at room temperature by the dip-coating technique. The obtained films were inserted to a furnace and annealed at 500°C for 60 min. The X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and optical transmittance were used to characterize the elaborated samples. XRD results show that the films have hexagonal structure and grow preferentially along the crystallographic direction (002). The average crystallite size estimated by the Scherrer formula is about 5 nm. FT-IR spectrometry showed all types of molecular vibrations in the films and confirmed the formation of a ZnO semiconductor in the samples. The refractive index and thickness of layers were determined from the optical transmittance spectra. We observed that an increase in the Al content in the solution leads to an increase in the films thickness and a decrease in their refractive index.Djouadi, D.Aksas, A.Chelouche, A.D.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 11, Iss 3, Pp 229-234 (2012) |
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Physics QC1-999 Electronics TK7800-8360 Djouadi, D. Aksas, A. Chelouche, A. Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method |
description |
Aluminum-doped zinc oxide thin films were deposited on glass substrates by the sol-gel technique. The effect of the Al concentration in the starting solution on the structural and optical properties of ZnO : Al thin films were studied. The molar ratio of the dopant (aluminum nitrate) in the solution [Al/Zn] was varied between 1% and 3%.The deposition of the layers was realized performed at room temperature by the dip-coating technique. The obtained films were inserted to a furnace and annealed at 500°C for 60 min. The X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and optical transmittance were used to characterize the elaborated samples. XRD results show that the films have hexagonal structure and grow preferentially along the crystallographic direction (002). The average crystallite size estimated by the Scherrer formula is about 5 nm. FT-IR spectrometry showed all types of molecular vibrations in the films and confirmed the formation of a ZnO semiconductor in the samples. The refractive index and thickness of layers were determined from the optical transmittance spectra. We observed that an increase in the Al content in the solution leads to an increase in the films thickness and a decrease in their refractive index. |
format |
article |
author |
Djouadi, D. Aksas, A. Chelouche, A. |
author_facet |
Djouadi, D. Aksas, A. Chelouche, A. |
author_sort |
Djouadi, D. |
title |
Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method |
title_short |
Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method |
title_full |
Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method |
title_fullStr |
Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method |
title_full_unstemmed |
Al-doping effects on the structural and optical properties of ZnO: al thin films prepared by the sol-gel method |
title_sort |
al-doping effects on the structural and optical properties of zno: al thin films prepared by the sol-gel method |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2012 |
url |
https://doaj.org/article/db5b83b4f86a4b2fb8d6482679158fdd |
work_keys_str_mv |
AT djouadid aldopingeffectsonthestructuralandopticalpropertiesofznoalthinfilmspreparedbythesolgelmethod AT aksasa aldopingeffectsonthestructuralandopticalpropertiesofznoalthinfilmspreparedbythesolgelmethod AT chelouchea aldopingeffectsonthestructuralandopticalpropertiesofznoalthinfilmspreparedbythesolgelmethod |
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