PEM anchorage on titanium using catechol grafting.
<h4>Background</h4>This study deals with the anchorage of polyelectrolyte films onto titanium surfaces via a cathecol-based linker for biomedical applications.<h4>Methodology</h4>The following study uses a molecule functionalized with a catechol and a carboxylic acid: 3-(3,4-...
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2012
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oai:doaj.org-article:db79ca63459b4e1096550aaa5b4afb022021-11-18T08:06:53ZPEM anchorage on titanium using catechol grafting.1932-620310.1371/journal.pone.0050326https://doaj.org/article/db79ca63459b4e1096550aaa5b4afb022012-01-01T00:00:00Zhttps://www.ncbi.nlm.nih.gov/pmc/articles/pmid/23226262/pdf/?tool=EBIhttps://doaj.org/toc/1932-6203<h4>Background</h4>This study deals with the anchorage of polyelectrolyte films onto titanium surfaces via a cathecol-based linker for biomedical applications.<h4>Methodology</h4>The following study uses a molecule functionalized with a catechol and a carboxylic acid: 3-(3,4-dihydroxyphenyl)propanoic acid. This molecule is anchored to the TiO(2) substrate via the catechol while the carboxylic acid reacts with polymers bearing amine groups. By providing a film anchorage of chemisorption type, it makes possible to deposit polyelectrolytes on the surface of titanium.<h4>Principal findings</h4>Infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), contact angle and atomic force microscopy (AFM) measurements show that the different steps of grafting have been successfully performed.<h4>Conclusions</h4>This method based on catechol anchorage of polyelectrolytes open a window towards large possibilities of clinical applications.Hélène MarieAmélie BarrereFrederic SchoensteinMarie-Hélène ChavanneBrigitte GrosgogeatLaurence MoraPublic Library of Science (PLoS)articleMedicineRScienceQENPLoS ONE, Vol 7, Iss 11, p e50326 (2012) |
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Medicine R Science Q Hélène Marie Amélie Barrere Frederic Schoenstein Marie-Hélène Chavanne Brigitte Grosgogeat Laurence Mora PEM anchorage on titanium using catechol grafting. |
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<h4>Background</h4>This study deals with the anchorage of polyelectrolyte films onto titanium surfaces via a cathecol-based linker for biomedical applications.<h4>Methodology</h4>The following study uses a molecule functionalized with a catechol and a carboxylic acid: 3-(3,4-dihydroxyphenyl)propanoic acid. This molecule is anchored to the TiO(2) substrate via the catechol while the carboxylic acid reacts with polymers bearing amine groups. By providing a film anchorage of chemisorption type, it makes possible to deposit polyelectrolytes on the surface of titanium.<h4>Principal findings</h4>Infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), contact angle and atomic force microscopy (AFM) measurements show that the different steps of grafting have been successfully performed.<h4>Conclusions</h4>This method based on catechol anchorage of polyelectrolytes open a window towards large possibilities of clinical applications. |
format |
article |
author |
Hélène Marie Amélie Barrere Frederic Schoenstein Marie-Hélène Chavanne Brigitte Grosgogeat Laurence Mora |
author_facet |
Hélène Marie Amélie Barrere Frederic Schoenstein Marie-Hélène Chavanne Brigitte Grosgogeat Laurence Mora |
author_sort |
Hélène Marie |
title |
PEM anchorage on titanium using catechol grafting. |
title_short |
PEM anchorage on titanium using catechol grafting. |
title_full |
PEM anchorage on titanium using catechol grafting. |
title_fullStr |
PEM anchorage on titanium using catechol grafting. |
title_full_unstemmed |
PEM anchorage on titanium using catechol grafting. |
title_sort |
pem anchorage on titanium using catechol grafting. |
publisher |
Public Library of Science (PLoS) |
publishDate |
2012 |
url |
https://doaj.org/article/db79ca63459b4e1096550aaa5b4afb02 |
work_keys_str_mv |
AT helenemarie pemanchorageontitaniumusingcatecholgrafting AT ameliebarrere pemanchorageontitaniumusingcatecholgrafting AT fredericschoenstein pemanchorageontitaniumusingcatecholgrafting AT mariehelenechavanne pemanchorageontitaniumusingcatecholgrafting AT brigittegrosgogeat pemanchorageontitaniumusingcatecholgrafting AT laurencemora pemanchorageontitaniumusingcatecholgrafting |
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