Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group

The synthesis of regio- and stereo-defined alkenes with multiple alkyl substituents is an unmet challenge. Here, the authors report a nickel-catalyzed intermolecular cross-dialkylation of alkynes devoid of directing or activating groups to afford multiple aliphatic substituted alkenes in a syn-selec...

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Autores principales:	Yi-Zhou Zhan, Nan Xiao, Wei Shu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/dbd054f7726943348617f8bc04247858
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spelling	oai:doaj.org-article:dbd054f7726943348617f8bc042478582021-12-02T13:30:07ZNi-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group10.1038/s41467-021-21083-w2041-1723https://doaj.org/article/dbd054f7726943348617f8bc042478582021-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21083-whttps://doaj.org/toc/2041-1723The synthesis of regio- and stereo-defined alkenes with multiple alkyl substituents is an unmet challenge. Here, the authors report a nickel-catalyzed intermolecular cross-dialkylation of alkynes devoid of directing or activating groups to afford multiple aliphatic substituted alkenes in a syn-selective fashion.Yi-Zhou ZhanNan XiaoWei ShuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yi-Zhou Zhan Nan Xiao Wei Shu Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
description	The synthesis of regio- and stereo-defined alkenes with multiple alkyl substituents is an unmet challenge. Here, the authors report a nickel-catalyzed intermolecular cross-dialkylation of alkynes devoid of directing or activating groups to afford multiple aliphatic substituted alkenes in a syn-selective fashion.
format	article
author	Yi-Zhou Zhan Nan Xiao Wei Shu
author_facet	Yi-Zhou Zhan Nan Xiao Wei Shu
author_sort	Yi-Zhou Zhan
title	Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
title_short	Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
title_full	Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
title_fullStr	Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
title_full_unstemmed	Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
title_sort	ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/dbd054f7726943348617f8bc04247858
work_keys_str_mv	AT yizhouzhan nicatalyzedregioandstereodefinedintermolecularcrosselectrophiledialkylationofalkyneswithoutdirectinggroup AT nanxiao nicatalyzedregioandstereodefinedintermolecularcrosselectrophiledialkylationofalkyneswithoutdirectinggroup AT weishu nicatalyzedregioandstereodefinedintermolecularcrosselectrophiledialkylationofalkyneswithoutdirectinggroup
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Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group

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