Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application

From the viewpoint of natural environmental requirement, the applications of biodegradable lubricants are growing. Most of vegetable oils are biodegradable and have good lubricating performance even at high contact pressure conditions in spite of their lower pressure-viscosity coefficient. In vegeta...

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Autores principales: Teruo Murakami, Hiroshi Sakamoto
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Lenguaje:EN
Publicado: Japanese Society of Tribologists 2008
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spelling oai:doaj.org-article:dbdd2267e4ea443fbe2c138403ab7f1e2021-11-05T09:28:53ZElucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application1881-219810.2474/trol.3.274https://doaj.org/article/dbdd2267e4ea443fbe2c138403ab7f1e2008-10-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/trol/3/5/3_5_274/_pdf/-char/enhttps://doaj.org/toc/1881-2198From the viewpoint of natural environmental requirement, the applications of biodegradable lubricants are growing. Most of vegetable oils are biodegradable and have good lubricating performance even at high contact pressure conditions in spite of their lower pressure-viscosity coefficient. In vegetable oils, however, the optimum suppression of oxidative degradation is required to improve the longevity of vegetable oils. Therefore, it is required to clarify the actual lubrication mechanism in vegetable oils with appropriate antioxidant additives. In this study, the tribological properties of four kinds of vegetable oils of different composition were evaluated in four-ball tests at different sliding speed conditions. As an antioxidant additive, α-tocopherol was used. The types of fatty acids in triglycerides appeared to control the lubricating performance through adsorbed film and friction polymer formation, depending on the operating conditions. Therefore, the paraffinic oils containing fatty acid were tested. It was shown that the influences of fatty acid types on lubricating performance were different depending on sliding speeds. These differences are discussed from the viewpoints of the role of friction polymer and oxidation of oils evaluated by FTIR analyses. Finally, effective application of various vegetable oils is discussed on the basis of relationship between tribological behaviors and operating conditions.Teruo MurakamiHiroshi SakamotoJapanese Society of Tribologistsarticlebiodegradable oilvegetable oilfriction polymerantioxidant additiveunsaturated fatty acidPhysicsQC1-999Engineering (General). Civil engineering (General)TA1-2040Mechanical engineering and machineryTJ1-1570ChemistryQD1-999ENTribology Online, Vol 3, Iss 5, Pp 274-279 (2008)
institution DOAJ
collection DOAJ
language EN
topic biodegradable oil
vegetable oil
friction polymer
antioxidant additive
unsaturated fatty acid
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
spellingShingle biodegradable oil
vegetable oil
friction polymer
antioxidant additive
unsaturated fatty acid
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
Teruo Murakami
Hiroshi Sakamoto
Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application
description From the viewpoint of natural environmental requirement, the applications of biodegradable lubricants are growing. Most of vegetable oils are biodegradable and have good lubricating performance even at high contact pressure conditions in spite of their lower pressure-viscosity coefficient. In vegetable oils, however, the optimum suppression of oxidative degradation is required to improve the longevity of vegetable oils. Therefore, it is required to clarify the actual lubrication mechanism in vegetable oils with appropriate antioxidant additives. In this study, the tribological properties of four kinds of vegetable oils of different composition were evaluated in four-ball tests at different sliding speed conditions. As an antioxidant additive, α-tocopherol was used. The types of fatty acids in triglycerides appeared to control the lubricating performance through adsorbed film and friction polymer formation, depending on the operating conditions. Therefore, the paraffinic oils containing fatty acid were tested. It was shown that the influences of fatty acid types on lubricating performance were different depending on sliding speeds. These differences are discussed from the viewpoints of the role of friction polymer and oxidation of oils evaluated by FTIR analyses. Finally, effective application of various vegetable oils is discussed on the basis of relationship between tribological behaviors and operating conditions.
format article
author Teruo Murakami
Hiroshi Sakamoto
author_facet Teruo Murakami
Hiroshi Sakamoto
author_sort Teruo Murakami
title Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application
title_short Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application
title_full Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application
title_fullStr Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application
title_full_unstemmed Elucidation of Lubrication Mechanism of Vegetable Oils and Their Effective Application
title_sort elucidation of lubrication mechanism of vegetable oils and their effective application
publisher Japanese Society of Tribologists
publishDate 2008
url https://doaj.org/article/dbdd2267e4ea443fbe2c138403ab7f1e
work_keys_str_mv AT teruomurakami elucidationoflubricationmechanismofvegetableoilsandtheireffectiveapplication
AT hiroshisakamoto elucidationoflubricationmechanismofvegetableoilsandtheireffectiveapplication
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