Putting pressure on aromaticity along with in situ experimental electron density of a molecular crystal
Aromatic compounds display enhanced stability due to delocalized π-bonding. Here, the authors study an aromatic, molecular crystal under pressure using x-ray diffraction and calculations, and observe a reduction in π-bond delocalization under increasing pressure.
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Autores principales: | , , , |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2016
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Materias: | |
Acceso en línea: | https://doaj.org/article/dbdd816c2b6a4c60a126c2445900df70 |
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Sumario: | Aromatic compounds display enhanced stability due to delocalized π-bonding. Here, the authors study an aromatic, molecular crystal under pressure using x-ray diffraction and calculations, and observe a reduction in π-bond delocalization under increasing pressure. |
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