Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules

α-Borylcarbonyl compounds are versatile synthons in organic synthesis, however their preparation is often tedious. Here, the authors report a regioselective radical α-borylation of α,β-unsaturated carbonyl compounds to afford α-borylcarbonyl molecules with high selectivity and functional group compa...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Shi-Chao Ren, Feng-Lian Zhang, Ai-Qing Xu, Yinuo Yang, Min Zheng, Xiaoguo Zhou, Yao Fu, Yi-Feng Wang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/dc9d93b0df7d48e9b233f69886c8cf94
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:dc9d93b0df7d48e9b233f69886c8cf94
record_format	dspace
spelling	oai:doaj.org-article:dc9d93b0df7d48e9b233f69886c8cf942021-12-02T16:57:19ZRegioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules10.1038/s41467-019-09825-32041-1723https://doaj.org/article/dc9d93b0df7d48e9b233f69886c8cf942019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09825-3https://doaj.org/toc/2041-1723α-Borylcarbonyl compounds are versatile synthons in organic synthesis, however their preparation is often tedious. Here, the authors report a regioselective radical α-borylation of α,β-unsaturated carbonyl compounds to afford α-borylcarbonyl molecules with high selectivity and functional group compatibility.Shi-Chao RenFeng-Lian ZhangAi-Qing XuYinuo YangMin ZhengXiaoguo ZhouYao FuYi-Feng WangNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shi-Chao Ren Feng-Lian Zhang Ai-Qing Xu Yinuo Yang Min Zheng Xiaoguo Zhou Yao Fu Yi-Feng Wang Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
description	α-Borylcarbonyl compounds are versatile synthons in organic synthesis, however their preparation is often tedious. Here, the authors report a regioselective radical α-borylation of α,β-unsaturated carbonyl compounds to afford α-borylcarbonyl molecules with high selectivity and functional group compatibility.
format	article
author	Shi-Chao Ren Feng-Lian Zhang Ai-Qing Xu Yinuo Yang Min Zheng Xiaoguo Zhou Yao Fu Yi-Feng Wang
author_facet	Shi-Chao Ren Feng-Lian Zhang Ai-Qing Xu Yinuo Yang Min Zheng Xiaoguo Zhou Yao Fu Yi-Feng Wang
author_sort	Shi-Chao Ren
title	Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
title_short	Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
title_full	Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
title_fullStr	Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
title_full_unstemmed	Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
title_sort	regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/dc9d93b0df7d48e9b233f69886c8cf94
work_keys_str_mv	AT shichaoren regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT fenglianzhang regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT aiqingxu regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT yinuoyang regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT minzheng regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT xiaoguozhou regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT yaofu regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules AT yifengwang regioselectiveradicalaborylationofabunsaturatedcarbonylcompoundsfordirectsynthesisofaborylcarbonylmolecules
_version_	1718382594339373056

Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules

Ejemplares similares