Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers

Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers

Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL) has attracted interest because it is biorenewable and exhibits superior properties to petroleum-based linear analog poly(methyl methacrylate) (PMMA). Here the authors report the synthesis of well-defined PMMBL-based ABA tri-block copolymers...

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Auteurs principaux: Yun Bai, Huaiyu Wang, Jianghua He, Yuetao Zhang, Eugene Y.-X. Chen
Format: article
Langue:EN
Publié: Nature Portfolio 2021
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Accès en ligne:https://doaj.org/article/dca36db6662b428ea1dee819f865e9ae
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spelling oai:doaj.org-article:dca36db6662b428ea1dee819f865e9ae2021-12-02T19:06:43ZDual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers10.1038/s41467-021-25069-62041-1723https://doaj.org/article/dca36db6662b428ea1dee819f865e9ae2021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25069-6https://doaj.org/toc/2041-1723Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL) has attracted interest because it is biorenewable and exhibits superior properties to petroleum-based linear analog poly(methyl methacrylate) (PMMA). Here the authors report the synthesis of well-defined PMMBL-based ABA tri-block copolymers, enabled by dual-initiating and living frustrated Lewis pairs, which have superior mechanical properties compared to those of PMMA-based tri-BCPs.Yun BaiHuaiyu WangJianghua HeYuetao ZhangEugene Y.-X. ChenNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yun Bai
Huaiyu Wang
Jianghua He
Yuetao Zhang
Eugene Y.-X. Chen
Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
description Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL) has attracted interest because it is biorenewable and exhibits superior properties to petroleum-based linear analog poly(methyl methacrylate) (PMMA). Here the authors report the synthesis of well-defined PMMBL-based ABA tri-block copolymers, enabled by dual-initiating and living frustrated Lewis pairs, which have superior mechanical properties compared to those of PMMA-based tri-BCPs.
format article
author Yun Bai
Huaiyu Wang
Jianghua He
Yuetao Zhang
Eugene Y.-X. Chen
author_facet Yun Bai
Huaiyu Wang
Jianghua He
Yuetao Zhang
Eugene Y.-X. Chen
author_sort Yun Bai
title Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_short Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_full Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_fullStr Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_full_unstemmed Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_sort dual-initiating and living frustrated lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/dca36db6662b428ea1dee819f865e9ae
work_keys_str_mv AT yunbai dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers
AT huaiyuwang dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers
AT jianghuahe dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers
AT yuetaozhang dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers
AT eugeneyxchen dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers
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