Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers

Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL) has attracted interest because it is biorenewable and exhibits superior properties to petroleum-based linear analog poly(methyl methacrylate) (PMMA). Here the authors report the synthesis of well-defined PMMBL-based ABA tri-block copolymers...

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Autores principales:	Yun Bai, Huaiyu Wang, Jianghua He, Yuetao Zhang, Eugene Y.-X. Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/dca36db6662b428ea1dee819f865e9ae
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spelling	oai:doaj.org-article:dca36db6662b428ea1dee819f865e9ae2021-12-02T19:06:43ZDual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers10.1038/s41467-021-25069-62041-1723https://doaj.org/article/dca36db6662b428ea1dee819f865e9ae2021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25069-6https://doaj.org/toc/2041-1723Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL) has attracted interest because it is biorenewable and exhibits superior properties to petroleum-based linear analog poly(methyl methacrylate) (PMMA). Here the authors report the synthesis of well-defined PMMBL-based ABA tri-block copolymers, enabled by dual-initiating and living frustrated Lewis pairs, which have superior mechanical properties compared to those of PMMA-based tri-BCPs.Yun BaiHuaiyu WangJianghua HeYuetao ZhangEugene Y.-X. ChenNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yun Bai Huaiyu Wang Jianghua He Yuetao Zhang Eugene Y.-X. Chen Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
description	Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL) has attracted interest because it is biorenewable and exhibits superior properties to petroleum-based linear analog poly(methyl methacrylate) (PMMA). Here the authors report the synthesis of well-defined PMMBL-based ABA tri-block copolymers, enabled by dual-initiating and living frustrated Lewis pairs, which have superior mechanical properties compared to those of PMMA-based tri-BCPs.
format	article
author	Yun Bai Huaiyu Wang Jianghua He Yuetao Zhang Eugene Y.-X. Chen
author_facet	Yun Bai Huaiyu Wang Jianghua He Yuetao Zhang Eugene Y.-X. Chen
author_sort	Yun Bai
title	Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_short	Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_full	Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_fullStr	Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_full_unstemmed	Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
title_sort	dual-initiating and living frustrated lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/dca36db6662b428ea1dee819f865e9ae
work_keys_str_mv	AT yunbai dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers AT huaiyuwang dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers AT jianghuahe dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers AT yuetaozhang dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers AT eugeneyxchen dualinitiatingandlivingfrustratedlewispairsexpeditioussynthesisofbiobasedthermoplasticelastomers
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Dual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers

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