Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials
The depleting and increasingly complex mineral resources bring challenges into the area of metal production, bringing new boundary conditions to the smelting and refining processes. Thermodynamics of phases and equilibria are the key to the analysis of pyrometallurgical processes, enabling descripti...
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MDPI AG
2021
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oai:doaj.org-article:dcaff73e76f94a2fa8f2b2d30daaee9e2021-11-25T19:04:37ZSimulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials10.3390/su1322128262071-1050https://doaj.org/article/dcaff73e76f94a2fa8f2b2d30daaee9e2021-11-01T00:00:00Zhttps://www.mdpi.com/2071-1050/13/22/12826https://doaj.org/toc/2071-1050The depleting and increasingly complex mineral resources bring challenges into the area of metal production, bringing new boundary conditions to the smelting and refining processes. Thermodynamics of phases and equilibria are the key to the analysis of pyrometallurgical processes, enabling descriptions of their limiting boundary conditions. The raw material basis of non-ferrous metals needs an effective control of iron oxide fluxing due to the challenging fact that the targeted metal values of, e.g., copper, nickel, lead, and tin will exist as minority components in the smelter feeds compared to iron sulphides, gangue, and many harmful elements. This means more complex slag compositions and the amount of produced slag being several times that of the metal production. This feature severely impacts the heat balance of the smelting vessels where autogenous operation without external fuels becomes more and more difficult to maintain.Pekka TaskinenKatri AvarmaaMDPI AGarticlecomputational thermodynamicsnon-ferrous metallurgyphase equilibriathermodynamicsEnvironmental effects of industries and plantsTD194-195Renewable energy sourcesTJ807-830Environmental sciencesGE1-350ENSustainability, Vol 13, Iss 12826, p 12826 (2021) |
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computational thermodynamics non-ferrous metallurgy phase equilibria thermodynamics Environmental effects of industries and plants TD194-195 Renewable energy sources TJ807-830 Environmental sciences GE1-350 |
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computational thermodynamics non-ferrous metallurgy phase equilibria thermodynamics Environmental effects of industries and plants TD194-195 Renewable energy sources TJ807-830 Environmental sciences GE1-350 Pekka Taskinen Katri Avarmaa Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials |
description |
The depleting and increasingly complex mineral resources bring challenges into the area of metal production, bringing new boundary conditions to the smelting and refining processes. Thermodynamics of phases and equilibria are the key to the analysis of pyrometallurgical processes, enabling descriptions of their limiting boundary conditions. The raw material basis of non-ferrous metals needs an effective control of iron oxide fluxing due to the challenging fact that the targeted metal values of, e.g., copper, nickel, lead, and tin will exist as minority components in the smelter feeds compared to iron sulphides, gangue, and many harmful elements. This means more complex slag compositions and the amount of produced slag being several times that of the metal production. This feature severely impacts the heat balance of the smelting vessels where autogenous operation without external fuels becomes more and more difficult to maintain. |
format |
article |
author |
Pekka Taskinen Katri Avarmaa |
author_facet |
Pekka Taskinen Katri Avarmaa |
author_sort |
Pekka Taskinen |
title |
Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials |
title_short |
Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials |
title_full |
Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials |
title_fullStr |
Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials |
title_full_unstemmed |
Simulation of Slag–Matte/Metal Equilibria for Complex and Low-Grade Raw Materials |
title_sort |
simulation of slag–matte/metal equilibria for complex and low-grade raw materials |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/dcaff73e76f94a2fa8f2b2d30daaee9e |
work_keys_str_mv |
AT pekkataskinen simulationofslagmattemetalequilibriaforcomplexandlowgraderawmaterials AT katriavarmaa simulationofslagmattemetalequilibriaforcomplexandlowgraderawmaterials |
_version_ |
1718410369019412480 |