Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst

Combining the Heck reaction with other transformations provides a powerful strategy to access diverse, complex compounds. Here, the authors report a weak coordination dominated Pd(0)-catalyzed quadruple C-H activation followed by hydro-functionalization, C-H silylation, and C-H borylation.

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Autores principales: Bo-Cheng Tang, Wen-Xuan Lin, Xiang-Long Chen, Cai He, Jin-Tian Ma, Yan-Dong Wu, Yu Lan, An-Xin Wu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/dcb375263fd8416e8482f782663f053d
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spelling oai:doaj.org-article:dcb375263fd8416e8482f782663f053d2021-12-02T14:42:56ZQuadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst10.1038/s41467-020-19508-z2041-1723https://doaj.org/article/dcb375263fd8416e8482f782663f053d2020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19508-zhttps://doaj.org/toc/2041-1723Combining the Heck reaction with other transformations provides a powerful strategy to access diverse, complex compounds. Here, the authors report a weak coordination dominated Pd(0)-catalyzed quadruple C-H activation followed by hydro-functionalization, C-H silylation, and C-H borylation.Bo-Cheng TangWen-Xuan LinXiang-Long ChenCai HeJin-Tian MaYan-Dong WuYu LanAn-Xin WuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-12 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Bo-Cheng Tang
Wen-Xuan Lin
Xiang-Long Chen
Cai He
Jin-Tian Ma
Yan-Dong Wu
Yu Lan
An-Xin Wu
Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
description Combining the Heck reaction with other transformations provides a powerful strategy to access diverse, complex compounds. Here, the authors report a weak coordination dominated Pd(0)-catalyzed quadruple C-H activation followed by hydro-functionalization, C-H silylation, and C-H borylation.
format article
author Bo-Cheng Tang
Wen-Xuan Lin
Xiang-Long Chen
Cai He
Jin-Tian Ma
Yan-Dong Wu
Yu Lan
An-Xin Wu
author_facet Bo-Cheng Tang
Wen-Xuan Lin
Xiang-Long Chen
Cai He
Jin-Tian Ma
Yan-Dong Wu
Yu Lan
An-Xin Wu
author_sort Bo-Cheng Tang
title Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
title_short Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
title_full Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
title_fullStr Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
title_full_unstemmed Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst
title_sort quadruple c-h activation coupled to hydrofunctionalization and c-h silylation/borylation enabled by weakly coordinated palladium catalyst
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/dcb375263fd8416e8482f782663f053d
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AT wenxuanlin quadruplechactivationcoupledtohydrofunctionalizationandchsilylationborylationenabledbyweaklycoordinatedpalladiumcatalyst
AT xianglongchen quadruplechactivationcoupledtohydrofunctionalizationandchsilylationborylationenabledbyweaklycoordinatedpalladiumcatalyst
AT caihe quadruplechactivationcoupledtohydrofunctionalizationandchsilylationborylationenabledbyweaklycoordinatedpalladiumcatalyst
AT jintianma quadruplechactivationcoupledtohydrofunctionalizationandchsilylationborylationenabledbyweaklycoordinatedpalladiumcatalyst
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AT yulan quadruplechactivationcoupledtohydrofunctionalizationandchsilylationborylationenabledbyweaklycoordinatedpalladiumcatalyst
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