Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests

Deracemization is a powerful method which allows transformation of racemic mixtures into excess enantiomer, but was applied only to small chiral molecular systems so far. Here the authors report deracemization of a kinetically stable bisporphyrin helicate upon encapsulation of chiral aromatic guests...

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Autores principales:	Naoki Ousaka, Shinya Yamamoto, Hiroki Iida, Takuya Iwata, Shingo Ito, Yuh Hijikata, Stephan Irle, Eiji Yashima
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/dcb941695a244bcebec89e46b6be6864
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spelling	oai:doaj.org-article:dcb941695a244bcebec89e46b6be68642021-12-02T14:39:20ZWater-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests10.1038/s41467-019-09443-z2041-1723https://doaj.org/article/dcb941695a244bcebec89e46b6be68642019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09443-zhttps://doaj.org/toc/2041-1723Deracemization is a powerful method which allows transformation of racemic mixtures into excess enantiomer, but was applied only to small chiral molecular systems so far. Here the authors report deracemization of a kinetically stable bisporphyrin helicate upon encapsulation of chiral aromatic guests.Naoki OusakaShinya YamamotoHiroki IidaTakuya IwataShingo ItoYuh HijikataStephan IrleEiji YashimaNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-11 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Naoki Ousaka Shinya Yamamoto Hiroki Iida Takuya Iwata Shingo Ito Yuh Hijikata Stephan Irle Eiji Yashima Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
description	Deracemization is a powerful method which allows transformation of racemic mixtures into excess enantiomer, but was applied only to small chiral molecular systems so far. Here the authors report deracemization of a kinetically stable bisporphyrin helicate upon encapsulation of chiral aromatic guests.
format	article
author	Naoki Ousaka Shinya Yamamoto Hiroki Iida Takuya Iwata Shingo Ito Yuh Hijikata Stephan Irle Eiji Yashima
author_facet	Naoki Ousaka Shinya Yamamoto Hiroki Iida Takuya Iwata Shingo Ito Yuh Hijikata Stephan Irle Eiji Yashima
author_sort	Naoki Ousaka
title	Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
title_short	Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
title_full	Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
title_fullStr	Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
title_full_unstemmed	Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
title_sort	water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/dcb941695a244bcebec89e46b6be6864
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Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests

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