Experimentally quantifying anion polarizability at the air/water interface

Understanding anion-specific interactions with hydrophobic interfaces is challenging due to an absence of local structural probes. Here, the authors experimentally quantify the anisotropy of perchlorate’s polarizability at the air/water interface, a window into anion and solvation shell structure.

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Auteurs principaux: Yujin Tong, Igor Ying Zhang, R. Kramer Campen
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/dd19b30623cf4b88a0170885a9fc0a97
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Résumé:Understanding anion-specific interactions with hydrophobic interfaces is challenging due to an absence of local structural probes. Here, the authors experimentally quantify the anisotropy of perchlorate’s polarizability at the air/water interface, a window into anion and solvation shell structure.