Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)

Abstract This study aims to analyze the products of the catalytic pyrolysis of naturally colored cotton residues, type BRS (seeds from Brazil), called BRS-Verde, BRS-Rubi, BRS-Topázio and BRS-Jade. The energy characterization of biomass was evaluated through ultimate and proximate analysis, higher h...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Janduir Egito da Silva, Guilherme Quintela Calixto, Rodolfo Luiz Bezerra de Araújo Medeiros, Marcus Antônio de Freitas Melo, Dulce Maria de Araújo Melo, Luiz Paulo de Carvalho, Renata Martins Braga
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/dd1bf902f08c4dc3b6be5d5135880162
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:dd1bf902f08c4dc3b6be5d5135880162
record_format	dspace
spelling	oai:doaj.org-article:dd1bf902f08c4dc3b6be5d51358801622021-12-02T16:27:45ZColored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)10.1038/s41598-021-95043-12045-2322https://doaj.org/article/dd1bf902f08c4dc3b6be5d51358801622021-08-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-95043-1https://doaj.org/toc/2045-2322Abstract This study aims to analyze the products of the catalytic pyrolysis of naturally colored cotton residues, type BRS (seeds from Brazil), called BRS-Verde, BRS-Rubi, BRS-Topázio and BRS-Jade. The energy characterization of biomass was evaluated through ultimate and proximate analysis, higher heating value, cellulose, hemicellulose and lignin content, thermogravimetric analysis and apparent density. Analytical pyrolysis was performed at 500 °C in an analytical pyrolyzer from CDS Analytical connected to a gas chromatograph coupled to the mass spectrometer (GC/MS). The pyrolysis vapors were reformed at 300 and 500 °C through thermal and catalytic cracking with zeolites (ZSM-5 and HZSM-5). It has been noticed that pyrolysis vapor reforming at 500 °C promoted partial deoxygenation and cracking reactions, while the catalytic reforming showed better results for the product deoxygenation. The catalyst reforming of pyrolysis products, especially using HZSM-5 at 500 °C, promoted the formation of monoaromatics such as benzene, toluene, xylene and styrene, which are important precursors of polymers, solvents and biofuels. The main influence on the yields of these aromatic products is due to the catalytic activity of ZSM-5 favored by increased temperature that promotes cracking reactions due expanded zeolites channels.Janduir Egito da SilvaGuilherme Quintela CalixtoRodolfo Luiz Bezerra de Araújo MedeirosMarcus Antônio de Freitas MeloDulce Maria de Araújo MeloLuiz Paulo de CarvalhoRenata Martins BragaNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Janduir Egito da Silva Guilherme Quintela Calixto Rodolfo Luiz Bezerra de Araújo Medeiros Marcus Antônio de Freitas Melo Dulce Maria de Araújo Melo Luiz Paulo de Carvalho Renata Martins Braga Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)
description	Abstract This study aims to analyze the products of the catalytic pyrolysis of naturally colored cotton residues, type BRS (seeds from Brazil), called BRS-Verde, BRS-Rubi, BRS-Topázio and BRS-Jade. The energy characterization of biomass was evaluated through ultimate and proximate analysis, higher heating value, cellulose, hemicellulose and lignin content, thermogravimetric analysis and apparent density. Analytical pyrolysis was performed at 500 °C in an analytical pyrolyzer from CDS Analytical connected to a gas chromatograph coupled to the mass spectrometer (GC/MS). The pyrolysis vapors were reformed at 300 and 500 °C through thermal and catalytic cracking with zeolites (ZSM-5 and HZSM-5). It has been noticed that pyrolysis vapor reforming at 500 °C promoted partial deoxygenation and cracking reactions, while the catalytic reforming showed better results for the product deoxygenation. The catalyst reforming of pyrolysis products, especially using HZSM-5 at 500 °C, promoted the formation of monoaromatics such as benzene, toluene, xylene and styrene, which are important precursors of polymers, solvents and biofuels. The main influence on the yields of these aromatic products is due to the catalytic activity of ZSM-5 favored by increased temperature that promotes cracking reactions due expanded zeolites channels.
format	article
author	Janduir Egito da Silva Guilherme Quintela Calixto Rodolfo Luiz Bezerra de Araújo Medeiros Marcus Antônio de Freitas Melo Dulce Maria de Araújo Melo Luiz Paulo de Carvalho Renata Martins Braga
author_facet	Janduir Egito da Silva Guilherme Quintela Calixto Rodolfo Luiz Bezerra de Araújo Medeiros Marcus Antônio de Freitas Melo Dulce Maria de Araújo Melo Luiz Paulo de Carvalho Renata Martins Braga
author_sort	Janduir Egito da Silva
title	Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)
title_short	Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)
title_full	Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)
title_fullStr	Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)
title_full_unstemmed	Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)
title_sort	colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (py-gc/ms)
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/dd1bf902f08c4dc3b6be5d5135880162
work_keys_str_mv	AT janduiregitodasilva coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms AT guilhermequintelacalixto coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms AT rodolfoluizbezerradearaujomedeiros coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms AT marcusantoniodefreitasmelo coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms AT dulcemariadearaujomelo coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms AT luizpaulodecarvalho coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms AT renatamartinsbraga coloredcottonwastesvaluationthroughthermalandcatalyticreformingofpyrolysisvaporspygcms
_version_	1718384022254518272

Colored cotton wastes valuation through thermal and catalytic reforming of pyrolysis vapors (Py-GC/MS)

Ejemplares similares