Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient alkenes, assisted by carbon disulfide and triph...

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Autores principales:	Hong-Mei Guo, Xuesong Wu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/dd2cbfe7dd664b6b9f188e8d4121d35a
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spelling	oai:doaj.org-article:dd2cbfe7dd664b6b9f188e8d4121d35a2021-12-02T14:55:15ZSelective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations10.1038/s41467-021-25702-42041-1723https://doaj.org/article/dd2cbfe7dd664b6b9f188e8d4121d35a2021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25702-4https://doaj.org/toc/2041-1723The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient alkenes, assisted by carbon disulfide and triphenylphosphine.Hong-Mei GuoXuesong WuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Hong-Mei Guo Xuesong Wu Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
description	The generation of alkyl radicals through deoxygenation of abundant alcohols via photoredox catalysis is of interest. In this study, the authors report a one-pot strategy for visible-light-promoted photoredox coupling of alcohols with electron-deficient alkenes, assisted by carbon disulfide and triphenylphosphine.
format	article
author	Hong-Mei Guo Xuesong Wu
author_facet	Hong-Mei Guo Xuesong Wu
author_sort	Hong-Mei Guo
title	Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_short	Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_full	Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_fullStr	Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_full_unstemmed	Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
title_sort	selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/dd2cbfe7dd664b6b9f188e8d4121d35a
work_keys_str_mv	AT hongmeiguo selectivedeoxygenativealkylationofalcoholsviaphotocatalyticdominoradicalfragmentations AT xuesongwu selectivedeoxygenativealkylationofalcoholsviaphotocatalyticdominoradicalfragmentations
_version_	1718389355200905216

Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations

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