Skeletal reorganization divergence of N-sulfonyl ynamides

Skeletal reorganizations are intriguing processes in chemical synthesis due to their mechanism, atom-economy and synthetic versatility. Herein, the authors describe a divergent skeletal reorganization of N-sulfonyl ynamides to thiete sulfones and propargyl sulfonamides.

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Detalles Bibliográficos
Autores principales: Linwei Zeng, Yuxin Lin, Jiaming Li, Hironao Sajiki, Hujun Xie, Sunliang Cui
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/dd9c238a04704969ba04b16577ef6e79
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Descripción
Sumario:Skeletal reorganizations are intriguing processes in chemical synthesis due to their mechanism, atom-economy and synthetic versatility. Herein, the authors describe a divergent skeletal reorganization of N-sulfonyl ynamides to thiete sulfones and propargyl sulfonamides.