Manipulating electron redistribution to achieve electronic pyroelectricity in molecular [FeCo] crystals

Pyroelectric materials exhibiting large and nearly constant pyroelectric coefficients over a wide temperature range are highly desirable. Here, the authors develop molecular [FeCo] crystals with continuous pyroelectricity, originating from a transition between three distinct electronic structures.

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Detalles Bibliográficos
Autores principales: Pritam Sadhukhan, Shu-Qi Wu, Jeremy Ian Long, Takumi Nakanishi, Shinji Kanegawa, Kaige Gao, Kaoru Yamamoto, Hajime Okajima, Akira Sakamoto, Michael L. Baker, Thomas Kroll, Dimosthenis Sokaras, Atsushi Okazawa, Norimichi Kojima, Yoshihito Shiota, Kazunari Yoshizawa, Osamu Sato
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/de38341e36a346469ee5e718ab7df818
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Descripción
Sumario:Pyroelectric materials exhibiting large and nearly constant pyroelectric coefficients over a wide temperature range are highly desirable. Here, the authors develop molecular [FeCo] crystals with continuous pyroelectricity, originating from a transition between three distinct electronic structures.