Weak functional group interactions revealed through metal-free active template rotaxane synthesis

Weak interactions between functional groups are often difficult to characterize in host–guest complexes. Here, the authors report the metal-free active template synthesis of a series of rotaxanes that permit a range of kinetically stabilized, weak crown ether-axle interactions to be characterized in...

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Autores principales:	Chong Tian, Stephen D. P. Fielden, George F. S. Whitehead, Iñigo J. Vitorica-Yrezabal, David A. Leigh
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/df052411bb3942a59fc814d14b135557
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spelling	oai:doaj.org-article:df052411bb3942a59fc814d14b1355572021-12-02T16:49:45ZWeak functional group interactions revealed through metal-free active template rotaxane synthesis10.1038/s41467-020-14576-72041-1723https://doaj.org/article/df052411bb3942a59fc814d14b1355572020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14576-7https://doaj.org/toc/2041-1723Weak interactions between functional groups are often difficult to characterize in host–guest complexes. Here, the authors report the metal-free active template synthesis of a series of rotaxanes that permit a range of kinetically stabilized, weak crown ether-axle interactions to be characterized in solution and the solid state.Chong TianStephen D. P. FieldenGeorge F. S. WhiteheadIñigo J. Vitorica-YrezabalDavid A. LeighNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chong Tian Stephen D. P. Fielden George F. S. Whitehead Iñigo J. Vitorica-Yrezabal David A. Leigh Weak functional group interactions revealed through metal-free active template rotaxane synthesis
description	Weak interactions between functional groups are often difficult to characterize in host–guest complexes. Here, the authors report the metal-free active template synthesis of a series of rotaxanes that permit a range of kinetically stabilized, weak crown ether-axle interactions to be characterized in solution and the solid state.
format	article
author	Chong Tian Stephen D. P. Fielden George F. S. Whitehead Iñigo J. Vitorica-Yrezabal David A. Leigh
author_facet	Chong Tian Stephen D. P. Fielden George F. S. Whitehead Iñigo J. Vitorica-Yrezabal David A. Leigh
author_sort	Chong Tian
title	Weak functional group interactions revealed through metal-free active template rotaxane synthesis
title_short	Weak functional group interactions revealed through metal-free active template rotaxane synthesis
title_full	Weak functional group interactions revealed through metal-free active template rotaxane synthesis
title_fullStr	Weak functional group interactions revealed through metal-free active template rotaxane synthesis
title_full_unstemmed	Weak functional group interactions revealed through metal-free active template rotaxane synthesis
title_sort	weak functional group interactions revealed through metal-free active template rotaxane synthesis
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/df052411bb3942a59fc814d14b135557
work_keys_str_mv	AT chongtian weakfunctionalgroupinteractionsrevealedthroughmetalfreeactivetemplaterotaxanesynthesis AT stephendpfielden weakfunctionalgroupinteractionsrevealedthroughmetalfreeactivetemplaterotaxanesynthesis AT georgefswhitehead weakfunctionalgroupinteractionsrevealedthroughmetalfreeactivetemplaterotaxanesynthesis AT inigojvitoricayrezabal weakfunctionalgroupinteractionsrevealedthroughmetalfreeactivetemplaterotaxanesynthesis AT davidaleigh weakfunctionalgroupinteractionsrevealedthroughmetalfreeactivetemplaterotaxanesynthesis
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Weak functional group interactions revealed through metal-free active template rotaxane synthesis

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