Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite
Heterogeneous photocatalysis using nanocomposites is of great research interest in the treatment of industrial wastewater. The impregnated photocatalyst was produced by liquid state reaction of ZnO/CuO nanocomposite with extracted eggshells. The structure, functional group, metal composition, bandga...
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oai:doaj.org-article:df0d7f01a05d40c89d7abeac25b0d1c52021-11-06T11:07:45ZRemediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite0273-12231996-973210.2166/wst.2021.165https://doaj.org/article/df0d7f01a05d40c89d7abeac25b0d1c52021-06-01T00:00:00Zhttp://wst.iwaponline.com/content/83/11/2753https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732Heterogeneous photocatalysis using nanocomposites is of great research interest in the treatment of industrial wastewater. The impregnated photocatalyst was produced by liquid state reaction of ZnO/CuO nanocomposite with extracted eggshells. The structure, functional group, metal composition, bandgap, and photocatalytic activity of the nanocomposites were characterized by using X-ray diffraction, Fourier-transform infrared spectroscopy, atomic absorption spectrometry, and UV–Vis spectroscopy, respectively, in the absence and presence of eggshells. Photocatalytic degradation activities of the nanocomposites under UV light irradiation have been tested for a real sewage sample taken from Debre Berhan Textile Industry. From the results, the optimized degradation efficiency of the dye was 97.95% with 0.4 g dose of the photocatalyst, 120 min irradiation time, 120 °C temperature, and pH of 6.7. The results revealed that eggshell impregnated nanocomposite had better catalytic activity than the naked nanocomposite. This is due to the highly porous structure of eggshell biomasses and their sorption characteristics. In conclusion, when nanocomposites are supported by eggshell biomasses, they are excellent photocatalysts and can minimize the contamination of organic dyes from textile effluents. HIGHLIGHTS Heterogeneous photocatalysis is a promising technology to remediate wastewater from industries.; Eggshell supported nanocomposites are effective for degradation of textile dyes under UV irradiation.; Waste eggshells can be recycled to support photocatalysts for wastewater treatment purposes.;Mekdes GeraworkIWA Publishingarticleindustrial wasteirradiationnanocompositesphphotocatalysisEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 11, Pp 2753-2761 (2021) |
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industrial waste irradiation nanocomposites ph photocatalysis Environmental technology. Sanitary engineering TD1-1066 |
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industrial waste irradiation nanocomposites ph photocatalysis Environmental technology. Sanitary engineering TD1-1066 Mekdes Gerawork Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite |
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Heterogeneous photocatalysis using nanocomposites is of great research interest in the treatment of industrial wastewater. The impregnated photocatalyst was produced by liquid state reaction of ZnO/CuO nanocomposite with extracted eggshells. The structure, functional group, metal composition, bandgap, and photocatalytic activity of the nanocomposites were characterized by using X-ray diffraction, Fourier-transform infrared spectroscopy, atomic absorption spectrometry, and UV–Vis spectroscopy, respectively, in the absence and presence of eggshells. Photocatalytic degradation activities of the nanocomposites under UV light irradiation have been tested for a real sewage sample taken from Debre Berhan Textile Industry. From the results, the optimized degradation efficiency of the dye was 97.95% with 0.4 g dose of the photocatalyst, 120 min irradiation time, 120 °C temperature, and pH of 6.7. The results revealed that eggshell impregnated nanocomposite had better catalytic activity than the naked nanocomposite. This is due to the highly porous structure of eggshell biomasses and their sorption characteristics. In conclusion, when nanocomposites are supported by eggshell biomasses, they are excellent photocatalysts and can minimize the contamination of organic dyes from textile effluents. HIGHLIGHTS
Heterogeneous photocatalysis is a promising technology to remediate wastewater from industries.;
Eggshell supported nanocomposites are effective for degradation of textile dyes under UV irradiation.;
Waste eggshells can be recycled to support photocatalysts for wastewater treatment purposes.; |
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Mekdes Gerawork |
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Mekdes Gerawork |
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Mekdes Gerawork |
title |
Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite |
title_short |
Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite |
title_full |
Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite |
title_fullStr |
Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite |
title_full_unstemmed |
Remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated ZnO/CuO nanocomposite |
title_sort |
remediation of textile industry organic dye waste by photocatalysis using eggshell impregnated zno/cuo nanocomposite |
publisher |
IWA Publishing |
publishDate |
2021 |
url |
https://doaj.org/article/df0d7f01a05d40c89d7abeac25b0d1c5 |
work_keys_str_mv |
AT mekdesgerawork remediationoftextileindustryorganicdyewastebyphotocatalysisusingeggshellimpregnatedznocuonanocomposite |
_version_ |
1718443764392919040 |