Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
Robust and selective C–H functionalisation of alkanes remains a challenge. Here, iodine(III) mediates the radical coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds in a range of cyclic and acyclic alkanes.
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Nature Portfolio
2021
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oai:doaj.org-article:df251398c7504812b5fad875ee9004612021-12-02T13:27:02ZIodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds10.1038/s42004-021-00480-82399-3669https://doaj.org/article/df251398c7504812b5fad875ee9004612021-03-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00480-8https://doaj.org/toc/2399-3669Robust and selective C–H functionalisation of alkanes remains a challenge. Here, iodine(III) mediates the radical coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds in a range of cyclic and acyclic alkanes.Fufang WuXuanzhen HanXuejian LiXiaobao ShenChang WangZhimei TianBin ChengJingbin ZhangLiangquan ShengHongbin ZhaiNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-7 (2021) |
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Chemistry QD1-999 |
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Chemistry QD1-999 Fufang Wu Xuanzhen Han Xuejian Li Xiaobao Shen Chang Wang Zhimei Tian Bin Cheng Jingbin Zhang Liangquan Sheng Hongbin Zhai Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds |
description |
Robust and selective C–H functionalisation of alkanes remains a challenge. Here, iodine(III) mediates the radical coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds in a range of cyclic and acyclic alkanes. |
format |
article |
author |
Fufang Wu Xuanzhen Han Xuejian Li Xiaobao Shen Chang Wang Zhimei Tian Bin Cheng Jingbin Zhang Liangquan Sheng Hongbin Zhai |
author_facet |
Fufang Wu Xuanzhen Han Xuejian Li Xiaobao Shen Chang Wang Zhimei Tian Bin Cheng Jingbin Zhang Liangquan Sheng Hongbin Zhai |
author_sort |
Fufang Wu |
title |
Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds |
title_short |
Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds |
title_full |
Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds |
title_fullStr |
Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds |
title_full_unstemmed |
Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds |
title_sort |
iodine(iii) promotes cross-dehydrogenative coupling of n-hydroxyphthalimide and unactivated c(sp3)–h bonds |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/df251398c7504812b5fad875ee900461 |
work_keys_str_mv |
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_version_ |
1718393063988002816 |