Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds

Robust and selective C–H functionalisation of alkanes remains a challenge. Here, iodine(III) mediates the radical coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds in a range of cyclic and acyclic alkanes.

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Autores principales: Fufang Wu, Xuanzhen Han, Xuejian Li, Xiaobao Shen, Chang Wang, Zhimei Tian, Bin Cheng, Jingbin Zhang, Liangquan Sheng, Hongbin Zhai
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/df251398c7504812b5fad875ee900461
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spelling oai:doaj.org-article:df251398c7504812b5fad875ee9004612021-12-02T13:27:02ZIodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds10.1038/s42004-021-00480-82399-3669https://doaj.org/article/df251398c7504812b5fad875ee9004612021-03-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00480-8https://doaj.org/toc/2399-3669Robust and selective C–H functionalisation of alkanes remains a challenge. Here, iodine(III) mediates the radical coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds in a range of cyclic and acyclic alkanes.Fufang WuXuanzhen HanXuejian LiXiaobao ShenChang WangZhimei TianBin ChengJingbin ZhangLiangquan ShengHongbin ZhaiNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-7 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chemistry
QD1-999
spellingShingle Chemistry
QD1-999
Fufang Wu
Xuanzhen Han
Xuejian Li
Xiaobao Shen
Chang Wang
Zhimei Tian
Bin Cheng
Jingbin Zhang
Liangquan Sheng
Hongbin Zhai
Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
description Robust and selective C–H functionalisation of alkanes remains a challenge. Here, iodine(III) mediates the radical coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds in a range of cyclic and acyclic alkanes.
format article
author Fufang Wu
Xuanzhen Han
Xuejian Li
Xiaobao Shen
Chang Wang
Zhimei Tian
Bin Cheng
Jingbin Zhang
Liangquan Sheng
Hongbin Zhai
author_facet Fufang Wu
Xuanzhen Han
Xuejian Li
Xiaobao Shen
Chang Wang
Zhimei Tian
Bin Cheng
Jingbin Zhang
Liangquan Sheng
Hongbin Zhai
author_sort Fufang Wu
title Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
title_short Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
title_full Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
title_fullStr Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
title_full_unstemmed Iodine(III) promotes cross-dehydrogenative coupling of N-hydroxyphthalimide and unactivated C(sp3)–H bonds
title_sort iodine(iii) promotes cross-dehydrogenative coupling of n-hydroxyphthalimide and unactivated c(sp3)–h bonds
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/df251398c7504812b5fad875ee900461
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