A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions

A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions

ATP acts as a co-substrate in enzyme catalysed reactions, but can also specifically bind metal ions. Here, the authors show that ATP interacts with copper ions and forms a Cu(II)-ATP complex that efficiently catalyses Diels-Alder reactions, and determine ATP residues that are essential for this acti...

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Autores principales: Changhao Wang, Qianqian Qi, Wenying Li, Jingshuang Dang, Min Hao, Shuting Lv, Xingchen Dong, Youkun Gu, Peizhe Wu, Wenyue Zhang, Yashao Chen, Jörg S. Hartig
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Science
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Acceso en línea:https://doaj.org/article/df90ccf5e4354cb09ee5fa636f1560e9
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