Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures

Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for enginee...

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Autores principales:	Zhida Gu, Wenlei Zhang, Ting Pan, Yu Shen, Peishan Qin, Peng Zhang, Xiaohan Li, Liwei Liu, Linjie Li, Yu Fu, Weina Zhang, Fengwei Huo
Formato:	article
Lenguaje:	EN
Publicado:	American Association for the Advancement of Science 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/dfa6178612bf44a98adc7ed997bbee1c
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id	oai:doaj.org-article:dfa6178612bf44a98adc7ed997bbee1c
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spelling	oai:doaj.org-article:dfa6178612bf44a98adc7ed997bbee1c2021-11-29T08:35:10ZAnisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures2639-527410.34133/2021/9854946https://doaj.org/article/dfa6178612bf44a98adc7ed997bbee1c2021-01-01T00:00:00Zhttp://dx.doi.org/10.34133/2021/9854946https://doaj.org/toc/2639-5274Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites.Zhida GuWenlei ZhangTing PanYu ShenPeishan QinPeng ZhangXiaohan LiLiwei LiuLinjie LiYu FuWeina ZhangFengwei HuoAmerican Association for the Advancement of SciencearticleScienceQENResearch, Vol 2021 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Zhida Gu Wenlei Zhang Ting Pan Yu Shen Peishan Qin Peng Zhang Xiaohan Li Liwei Liu Linjie Li Yu Fu Weina Zhang Fengwei Huo Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
description	Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites.
format	article
author	Zhida Gu Wenlei Zhang Ting Pan Yu Shen Peishan Qin Peng Zhang Xiaohan Li Liwei Liu Linjie Li Yu Fu Weina Zhang Fengwei Huo
author_facet	Zhida Gu Wenlei Zhang Ting Pan Yu Shen Peishan Qin Peng Zhang Xiaohan Li Liwei Liu Linjie Li Yu Fu Weina Zhang Fengwei Huo
author_sort	Zhida Gu
title	Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
title_short	Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
title_full	Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
title_fullStr	Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
title_full_unstemmed	Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
title_sort	anisotropic mof-on-mof growth of isostructural multilayer metal–organic framework heterostructures
publisher	American Association for the Advancement of Science
publishDate	2021
url	https://doaj.org/article/dfa6178612bf44a98adc7ed997bbee1c
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Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures

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