Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites

Cellulose acetate (CA) is widely used as an alternative to conventional plastics because of the minor environmental impact of its decomposition cycle. This study synthesized five-layer environmentally friendly composites from CA bioplastic and basalt fibers (BFs) to produce a high-strength marine-bi...

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Autores principales: Yuxi Shen, Alia Gallet-Pandellé, Hiroki Kurita, Fumio Narita
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/dfd169144a944fbe9ca4889d4302200f
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spelling oai:doaj.org-article:dfd169144a944fbe9ca4889d4302200f2021-11-25T18:48:41ZFabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites10.3390/polym132239442073-4360https://doaj.org/article/dfd169144a944fbe9ca4889d4302200f2021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3944https://doaj.org/toc/2073-4360Cellulose acetate (CA) is widely used as an alternative to conventional plastics because of the minor environmental impact of its decomposition cycle. This study synthesized five-layer environmentally friendly composites from CA bioplastic and basalt fibers (BFs) to produce a high-strength marine-biodegradable polymer. Maleic anhydride-grafted polypropylene (PP-g-MAH) was mixed with CA as a surface-active agent (SAA) to understand the effect of surface treatment on the mechanical properties of the composite. Tensile tests and scanning electron microscopy were conducted to observe the fracture surfaces. The ultimate tensile strength (UTS) of the BF/CA composite increased by approximately a factor of 4 after adding 11 vol.% unidirectional BF. When the SAA was added, the UTS of the composite with 11 vol.% BF was multiplied by a factor of about 7, which indicates that the surface treatment has a significant positive effect on the mechanical properties. However, the improvement is not apparent when the added BFs are in a plain weave with a vertical orientation. A photodecomposition experiment was then conducted by adding TiO<sub>2</sub>. Observing the UTS changes of the CA and BF/CA composites, the effect of the photocatalyst on the decomposition of the materials was explored.Yuxi ShenAlia Gallet-PandelléHiroki KuritaFumio NaritaMDPI AGarticlemechanical testingnatural fiberspolymer matrix composites (PMCs)strengthenvironmental degradationOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3944, p 3944 (2021)
institution DOAJ
collection DOAJ
language EN
topic mechanical testing
natural fibers
polymer matrix composites (PMCs)
strength
environmental degradation
Organic chemistry
QD241-441
spellingShingle mechanical testing
natural fibers
polymer matrix composites (PMCs)
strength
environmental degradation
Organic chemistry
QD241-441
Yuxi Shen
Alia Gallet-Pandellé
Hiroki Kurita
Fumio Narita
Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites
description Cellulose acetate (CA) is widely used as an alternative to conventional plastics because of the minor environmental impact of its decomposition cycle. This study synthesized five-layer environmentally friendly composites from CA bioplastic and basalt fibers (BFs) to produce a high-strength marine-biodegradable polymer. Maleic anhydride-grafted polypropylene (PP-g-MAH) was mixed with CA as a surface-active agent (SAA) to understand the effect of surface treatment on the mechanical properties of the composite. Tensile tests and scanning electron microscopy were conducted to observe the fracture surfaces. The ultimate tensile strength (UTS) of the BF/CA composite increased by approximately a factor of 4 after adding 11 vol.% unidirectional BF. When the SAA was added, the UTS of the composite with 11 vol.% BF was multiplied by a factor of about 7, which indicates that the surface treatment has a significant positive effect on the mechanical properties. However, the improvement is not apparent when the added BFs are in a plain weave with a vertical orientation. A photodecomposition experiment was then conducted by adding TiO<sub>2</sub>. Observing the UTS changes of the CA and BF/CA composites, the effect of the photocatalyst on the decomposition of the materials was explored.
format article
author Yuxi Shen
Alia Gallet-Pandellé
Hiroki Kurita
Fumio Narita
author_facet Yuxi Shen
Alia Gallet-Pandellé
Hiroki Kurita
Fumio Narita
author_sort Yuxi Shen
title Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites
title_short Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites
title_full Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites
title_fullStr Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites
title_full_unstemmed Fabrication, Tensile Properties, and Photodecomposition of Basalt Fiber-Reinforced Cellulose Acetate Matrix Composites
title_sort fabrication, tensile properties, and photodecomposition of basalt fiber-reinforced cellulose acetate matrix composites
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/dfd169144a944fbe9ca4889d4302200f
work_keys_str_mv AT yuxishen fabricationtensilepropertiesandphotodecompositionofbasaltfiberreinforcedcelluloseacetatematrixcomposites
AT aliagalletpandelle fabricationtensilepropertiesandphotodecompositionofbasaltfiberreinforcedcelluloseacetatematrixcomposites
AT hirokikurita fabricationtensilepropertiesandphotodecompositionofbasaltfiberreinforcedcelluloseacetatematrixcomposites
AT fumionarita fabricationtensilepropertiesandphotodecompositionofbasaltfiberreinforcedcelluloseacetatematrixcomposites
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