Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate

The title compound, [Co6Hg2(C5H5)6(C5H4Se)6](PF6)4·2CH3CN or [Hg2(CcSe)6][PF6]4·2CH3CN (Cc = C10H9Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four hexafluoridophosphate counter-ions and...

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Autores principales:	Daniel Menia, Klaus Wurst, Benno Bildstein
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	cobalt selenium mercury sandwich complexes crystal structure Crystallography QD901-999
Acceso en línea:	https://doaj.org/article/e0d1752f34c24faea3b0c5d2bf218ad0
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spelling	oai:doaj.org-article:e0d1752f34c24faea3b0c5d2bf218ad02021-11-12T12:26:16ZBis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate2414-314610.1107/S241431462101083Xhttps://doaj.org/article/e0d1752f34c24faea3b0c5d2bf218ad02021-10-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S241431462101083Xhttps://doaj.org/toc/2414-3146The title compound, [Co6Hg2(C5H5)6(C5H4Se)6](PF6)4·2CH3CN or [Hg2(CcSe)6][PF6]4·2CH3CN (Cc = C10H9Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four hexafluoridophosphate counter-ions and two acetonitrile solvent molecules. The cation (point group \overline{1}) has a bitetrahedral {Hg2Se6} core with two bridging Se atoms and four terminal Se atoms.Daniel MeniaKlaus WurstBenno BildsteinInternational Union of Crystallographyarticlecobaltseleniummercurysandwich complexescrystal structureCrystallographyQD901-999ENIUCrData, Vol 6, Iss 10, p x211083 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	cobalt selenium mercury sandwich complexes crystal structure Crystallography QD901-999
spellingShingle	cobalt selenium mercury sandwich complexes crystal structure Crystallography QD901-999 Daniel Menia Klaus Wurst Benno Bildstein Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
description	The title compound, [Co6Hg2(C5H5)6(C5H4Se)6](PF6)4·2CH3CN or [Hg2(CcSe)6][PF6]4·2CH3CN (Cc = C10H9Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four hexafluoridophosphate counter-ions and two acetonitrile solvent molecules. The cation (point group \overline{1}) has a bitetrahedral {Hg2Se6} core with two bridging Se atoms and four terminal Se atoms.
format	article
author	Daniel Menia Klaus Wurst Benno Bildstein
author_facet	Daniel Menia Klaus Wurst Benno Bildstein
author_sort	Daniel Menia
title	Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
title_short	Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
title_full	Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
title_fullStr	Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
title_full_unstemmed	Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
title_sort	bis(μ-cobaltoceniumselenolate-1:2κ2se:se)bis[bis(cobaltoceniumselenolate-κse)mercury(ii)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/e0d1752f34c24faea3b0c5d2bf218ad0
work_keys_str_mv	AT danielmenia bismcobaltoceniumselenolate12k2sesebisbiscobaltoceniumselenolateksemercuryiitetrakishexafluoridophosphateacetonitriledisolvate AT klauswurst bismcobaltoceniumselenolate12k2sesebisbiscobaltoceniumselenolateksemercuryiitetrakishexafluoridophosphateacetonitriledisolvate AT bennobildstein bismcobaltoceniumselenolate12k2sesebisbiscobaltoceniumselenolateksemercuryiitetrakishexafluoridophosphateacetonitriledisolvate
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Bis(μ-cobaltoceniumselenolate-1:2κ2Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate

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