Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne

Catalytic methodologies that incorporate commodity chemicals ethylene and ethyne into fine chemicals are quite limited. Here, the authors show a cobalt-catalyzed electrochemical C-H/N–H [4+2] annulation of aryl/vinyl amides with ethylene or ethyne to produce N-heterocycles in absence of oxidants.

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Autores principales: Shan Tang, Dan Wang, Yichang Liu, Li Zeng, Aiwen Lei
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/e0e88c760e5843bba879a51cfd65832f
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spelling oai:doaj.org-article:e0e88c760e5843bba879a51cfd65832f2021-12-02T17:31:26ZCobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne10.1038/s41467-018-03246-42041-1723https://doaj.org/article/e0e88c760e5843bba879a51cfd65832f2018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03246-4https://doaj.org/toc/2041-1723Catalytic methodologies that incorporate commodity chemicals ethylene and ethyne into fine chemicals are quite limited. Here, the authors show a cobalt-catalyzed electrochemical C-H/N–H [4+2] annulation of aryl/vinyl amides with ethylene or ethyne to produce N-heterocycles in absence of oxidants.Shan TangDan WangYichang LiuLi ZengAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Shan Tang
Dan Wang
Yichang Liu
Li Zeng
Aiwen Lei
Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
description Catalytic methodologies that incorporate commodity chemicals ethylene and ethyne into fine chemicals are quite limited. Here, the authors show a cobalt-catalyzed electrochemical C-H/N–H [4+2] annulation of aryl/vinyl amides with ethylene or ethyne to produce N-heterocycles in absence of oxidants.
format article
author Shan Tang
Dan Wang
Yichang Liu
Li Zeng
Aiwen Lei
author_facet Shan Tang
Dan Wang
Yichang Liu
Li Zeng
Aiwen Lei
author_sort Shan Tang
title Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
title_short Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
title_full Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
title_fullStr Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
title_full_unstemmed Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne
title_sort cobalt-catalyzed electrooxidative c-h/n-h [4+2] annulation with ethylene or ethyne
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/e0e88c760e5843bba879a51cfd65832f
work_keys_str_mv AT shantang cobaltcatalyzedelectrooxidativechnh42annulationwithethyleneorethyne
AT danwang cobaltcatalyzedelectrooxidativechnh42annulationwithethyleneorethyne
AT yichangliu cobaltcatalyzedelectrooxidativechnh42annulationwithethyleneorethyne
AT lizeng cobaltcatalyzedelectrooxidativechnh42annulationwithethyleneorethyne
AT aiwenlei cobaltcatalyzedelectrooxidativechnh42annulationwithethyleneorethyne
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