A broadly tunable synthesis of linear α-olefins
Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts...
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Nature Portfolio
2017
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oai:doaj.org-article:e1005b759b0c4923bd5bb146d5ee05a72021-12-02T14:42:37ZA broadly tunable synthesis of linear α-olefins10.1038/s41467-017-01507-22041-1723https://doaj.org/article/e1005b759b0c4923bd5bb146d5ee05a72017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01507-2https://doaj.org/toc/2041-1723Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts.Andreas GollwitzerThomas DietelWinfried P. KretschmerRhett KempeNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017) |
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Science Q Andreas Gollwitzer Thomas Dietel Winfried P. Kretschmer Rhett Kempe A broadly tunable synthesis of linear α-olefins |
description |
Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts. |
format |
article |
author |
Andreas Gollwitzer Thomas Dietel Winfried P. Kretschmer Rhett Kempe |
author_facet |
Andreas Gollwitzer Thomas Dietel Winfried P. Kretschmer Rhett Kempe |
author_sort |
Andreas Gollwitzer |
title |
A broadly tunable synthesis of linear α-olefins |
title_short |
A broadly tunable synthesis of linear α-olefins |
title_full |
A broadly tunable synthesis of linear α-olefins |
title_fullStr |
A broadly tunable synthesis of linear α-olefins |
title_full_unstemmed |
A broadly tunable synthesis of linear α-olefins |
title_sort |
broadly tunable synthesis of linear α-olefins |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/e1005b759b0c4923bd5bb146d5ee05a7 |
work_keys_str_mv |
AT andreasgollwitzer abroadlytunablesynthesisoflinearaolefins AT thomasdietel abroadlytunablesynthesisoflinearaolefins AT winfriedpkretschmer abroadlytunablesynthesisoflinearaolefins AT rhettkempe abroadlytunablesynthesisoflinearaolefins AT andreasgollwitzer broadlytunablesynthesisoflinearaolefins AT thomasdietel broadlytunablesynthesisoflinearaolefins AT winfriedpkretschmer broadlytunablesynthesisoflinearaolefins AT rhettkempe broadlytunablesynthesisoflinearaolefins |
_version_ |
1718389662956912640 |