A broadly tunable synthesis of linear α-olefins

Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts...

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Auteurs principaux: Andreas Gollwitzer, Thomas Dietel, Winfried P. Kretschmer, Rhett Kempe
Format: article
Langue:EN
Publié: Nature Portfolio 2017
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Accès en ligne:https://doaj.org/article/e1005b759b0c4923bd5bb146d5ee05a7
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spelling oai:doaj.org-article:e1005b759b0c4923bd5bb146d5ee05a72021-12-02T14:42:37ZA broadly tunable synthesis of linear α-olefins10.1038/s41467-017-01507-22041-1723https://doaj.org/article/e1005b759b0c4923bd5bb146d5ee05a72017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01507-2https://doaj.org/toc/2041-1723Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts.Andreas GollwitzerThomas DietelWinfried P. KretschmerRhett KempeNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Andreas Gollwitzer
Thomas Dietel
Winfried P. Kretschmer
Rhett Kempe
A broadly tunable synthesis of linear α-olefins
description Linear α-olefins are important bulk chemicals annually produced in megaton scale. Here, the authors report a trimetallic catalyst system for the synthesis of 1-butene and a broad range of α-olefins and achieve control over chain length by tuning the reaction rates of the nickel and yttrium catalysts.
format article
author Andreas Gollwitzer
Thomas Dietel
Winfried P. Kretschmer
Rhett Kempe
author_facet Andreas Gollwitzer
Thomas Dietel
Winfried P. Kretschmer
Rhett Kempe
author_sort Andreas Gollwitzer
title A broadly tunable synthesis of linear α-olefins
title_short A broadly tunable synthesis of linear α-olefins
title_full A broadly tunable synthesis of linear α-olefins
title_fullStr A broadly tunable synthesis of linear α-olefins
title_full_unstemmed A broadly tunable synthesis of linear α-olefins
title_sort broadly tunable synthesis of linear α-olefins
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/e1005b759b0c4923bd5bb146d5ee05a7
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AT rhettkempe abroadlytunablesynthesisoflinearaolefins
AT andreasgollwitzer broadlytunablesynthesisoflinearaolefins
AT thomasdietel broadlytunablesynthesisoflinearaolefins
AT winfriedpkretschmer broadlytunablesynthesisoflinearaolefins
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