Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy

Understanding enzyme active sites can elucidate fundamental enzymatic reaction pathways and inform designs for synthetic catalysts. Here, authors employ operando X-ray absorption spectroelectrochemistry to assess copper ions in bilirubin oxidase during oxygen reduction electrocatalysis.

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Autores principales:	Lucyano J. A. Macedo, Ayaz Hassan, Graziela C. Sedenho, Frank N. Crespilho
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e11515873a8c404589a53165c6a77d4e
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spelling	oai:doaj.org-article:e11515873a8c404589a53165c6a77d4e2021-12-02T17:32:57ZAssessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy10.1038/s41467-019-14210-12041-1723https://doaj.org/article/e11515873a8c404589a53165c6a77d4e2020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-14210-1https://doaj.org/toc/2041-1723Understanding enzyme active sites can elucidate fundamental enzymatic reaction pathways and inform designs for synthetic catalysts. Here, authors employ operando X-ray absorption spectroelectrochemistry to assess copper ions in bilirubin oxidase during oxygen reduction electrocatalysis.Lucyano J. A. MacedoAyaz HassanGraziela C. SedenhoFrank N. CrespilhoNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lucyano J. A. Macedo Ayaz Hassan Graziela C. Sedenho Frank N. Crespilho Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy
description	Understanding enzyme active sites can elucidate fundamental enzymatic reaction pathways and inform designs for synthetic catalysts. Here, authors employ operando X-ray absorption spectroelectrochemistry to assess copper ions in bilirubin oxidase during oxygen reduction electrocatalysis.
format	article
author	Lucyano J. A. Macedo Ayaz Hassan Graziela C. Sedenho Frank N. Crespilho
author_facet	Lucyano J. A. Macedo Ayaz Hassan Graziela C. Sedenho Frank N. Crespilho
author_sort	Lucyano J. A. Macedo
title	Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy
title_short	Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy
title_full	Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy
title_fullStr	Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy
title_full_unstemmed	Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy
title_sort	assessing electron transfer reactions and catalysis in multicopper oxidases with operando x-ray absorption spectroscopy
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/e11515873a8c404589a53165c6a77d4e
work_keys_str_mv	AT lucyanojamacedo assessingelectrontransferreactionsandcatalysisinmulticopperoxidaseswithoperandoxrayabsorptionspectroscopy AT ayazhassan assessingelectrontransferreactionsandcatalysisinmulticopperoxidaseswithoperandoxrayabsorptionspectroscopy AT grazielacsedenho assessingelectrontransferreactionsandcatalysisinmulticopperoxidaseswithoperandoxrayabsorptionspectroscopy AT frankncrespilho assessingelectrontransferreactionsandcatalysisinmulticopperoxidaseswithoperandoxrayabsorptionspectroscopy
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Assessing electron transfer reactions and catalysis in multicopper oxidases with operando X-ray absorption spectroscopy

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