Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria

Samples of ∼1 µm films of CeO2 doped with 2 wt% Mo, 1.5 wt% Ru, 0.75 wt% Pd, 0.5 wt% Re and 0.25 wt% Rh grown with pulsed laser deposition were irradiated with I2+ ions (610 °C and 730 °C, 1016 and 5 × 1016 I2+/cm2). For selected samples post-irradiation heat treatment was conducted (900 °C, 1100 °C...

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Autores principales:	Karen Kruska, Weilin Jiang, Xuemei Wang, Lin Shao, Brian J. Riley, Ram Devanathan
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Multicomponent alloy ε-phase STEM EDS Atom-probe tomography Surrogate fuel Ion irradiation Computer applications to medicine. Medical informatics R858-859.7 Science (General) Q1-390
Acceso en línea:	https://doaj.org/article/e1d65353bbd34e35a416b8e5388a99a3
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spelling	oai:doaj.org-article:e1d65353bbd34e35a416b8e5388a99a32021-11-20T05:06:53ZEnergy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria2352-340910.1016/j.dib.2021.107460https://doaj.org/article/e1d65353bbd34e35a416b8e5388a99a32021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2352340921007423https://doaj.org/toc/2352-3409Samples of ∼1 µm films of CeO2 doped with 2 wt% Mo, 1.5 wt% Ru, 0.75 wt% Pd, 0.5 wt% Re and 0.25 wt% Rh grown with pulsed laser deposition were irradiated with I2+ ions (610 °C and 730 °C, 1016 and 5 × 1016 I2+/cm2). For selected samples post-irradiation heat treatment was conducted (900 °C, 1100 °C). The specimens were sectioned with focused ion beam milling and characterized in a transmission electron microscope with energy-dispersive x-ray spectroscopy, and with atom-probe tomography. Energy-dispersive x-ray spectroscopy was used to obtain elemental maps showing the distribution of dopants in the specimen after exposure. Some of these maps are discussed in detail in our companion article “Formation of multicomponent alloy particles in doped ceria under I2+ ion irradiation and thermal annealing” in the Journal of Nuclear Materials [1]. Advanced computational analysis could be used to more accurately quantify local compositions. Data is provided for additional regions of interest and one additional irradiation condition.The doped ceria film that was heat treated at 1100 °C delaminated from the substrate in most places. Samples were extracted from the underside of a delaminated piece and analyzed with atom-probe tomography. The resulting data show ceria and a Mo-rich particle and demonstrate that this approach is feasable in principle to study local compositions in a sample exposed to such extreme conditions.Karen KruskaWeilin JiangXuemei WangLin ShaoBrian J. RileyRam DevanathanElsevierarticleMulticomponent alloyε-phaseSTEM EDSAtom-probe tomographySurrogate fuelIon irradiationComputer applications to medicine. Medical informaticsR858-859.7Science (General)Q1-390ENData in Brief, Vol 39, Iss , Pp 107460- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Multicomponent alloy ε-phase STEM EDS Atom-probe tomography Surrogate fuel Ion irradiation Computer applications to medicine. Medical informatics R858-859.7 Science (General) Q1-390
spellingShingle	Multicomponent alloy ε-phase STEM EDS Atom-probe tomography Surrogate fuel Ion irradiation Computer applications to medicine. Medical informatics R858-859.7 Science (General) Q1-390 Karen Kruska Weilin Jiang Xuemei Wang Lin Shao Brian J. Riley Ram Devanathan Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
description	Samples of ∼1 µm films of CeO2 doped with 2 wt% Mo, 1.5 wt% Ru, 0.75 wt% Pd, 0.5 wt% Re and 0.25 wt% Rh grown with pulsed laser deposition were irradiated with I2+ ions (610 °C and 730 °C, 1016 and 5 × 1016 I2+/cm2). For selected samples post-irradiation heat treatment was conducted (900 °C, 1100 °C). The specimens were sectioned with focused ion beam milling and characterized in a transmission electron microscope with energy-dispersive x-ray spectroscopy, and with atom-probe tomography. Energy-dispersive x-ray spectroscopy was used to obtain elemental maps showing the distribution of dopants in the specimen after exposure. Some of these maps are discussed in detail in our companion article “Formation of multicomponent alloy particles in doped ceria under I2+ ion irradiation and thermal annealing” in the Journal of Nuclear Materials [1]. Advanced computational analysis could be used to more accurately quantify local compositions. Data is provided for additional regions of interest and one additional irradiation condition.The doped ceria film that was heat treated at 1100 °C delaminated from the substrate in most places. Samples were extracted from the underside of a delaminated piece and analyzed with atom-probe tomography. The resulting data show ceria and a Mo-rich particle and demonstrate that this approach is feasable in principle to study local compositions in a sample exposed to such extreme conditions.
format	article
author	Karen Kruska Weilin Jiang Xuemei Wang Lin Shao Brian J. Riley Ram Devanathan
author_facet	Karen Kruska Weilin Jiang Xuemei Wang Lin Shao Brian J. Riley Ram Devanathan
author_sort	Karen Kruska
title	Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
title_short	Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
title_full	Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
title_fullStr	Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
title_full_unstemmed	Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
title_sort	energy-dispersive x-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/e1d65353bbd34e35a416b8e5388a99a3
work_keys_str_mv	AT karenkruska energydispersivexrayspectroscopyandatomprobetomographydataquantifyingcomponentratiosofmulticomponentnanoprecipitatesinionirradiatedceria AT weilinjiang energydispersivexrayspectroscopyandatomprobetomographydataquantifyingcomponentratiosofmulticomponentnanoprecipitatesinionirradiatedceria AT xuemeiwang energydispersivexrayspectroscopyandatomprobetomographydataquantifyingcomponentratiosofmulticomponentnanoprecipitatesinionirradiatedceria AT linshao energydispersivexrayspectroscopyandatomprobetomographydataquantifyingcomponentratiosofmulticomponentnanoprecipitatesinionirradiatedceria AT brianjriley energydispersivexrayspectroscopyandatomprobetomographydataquantifyingcomponentratiosofmulticomponentnanoprecipitatesinionirradiatedceria AT ramdevanathan energydispersivexrayspectroscopyandatomprobetomographydataquantifyingcomponentratiosofmulticomponentnanoprecipitatesinionirradiatedceria
_version_	1718419629247823872

Energy-dispersive X-ray spectroscopy and atom-probe tomography data quantifying component-ratios of multicomponent nano-precipitates in ion-irradiated ceria

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