Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules

Coupling reactions to form C–C bonds typically require transition metals. Here the authors report that an organoboron compound can allow sequential alkyne insertion and unusual oxidative deborylation/Csp2 –Csp2 coupling, enabling the transformation of acetylenes into extended π-conjugated molecules....

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Autores principales:	Yoshiaki Shoji, Naoki Tanaka, Sho Muranaka, Naoki Shigeno, Haruka Sugiyama, Kumiko Takenouchi, Fatin Hajjaj, Takanori Fukushima
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e1d89bd51ba0497d86ef4fe23d35f06a
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spelling	oai:doaj.org-article:e1d89bd51ba0497d86ef4fe23d35f06a2021-12-02T17:31:49ZBoron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules10.1038/ncomms127042041-1723https://doaj.org/article/e1d89bd51ba0497d86ef4fe23d35f06a2016-09-01T00:00:00Zhttps://doi.org/10.1038/ncomms12704https://doaj.org/toc/2041-1723Coupling reactions to form C–C bonds typically require transition metals. Here the authors report that an organoboron compound can allow sequential alkyne insertion and unusual oxidative deborylation/Csp2 –Csp2 coupling, enabling the transformation of acetylenes into extended π-conjugated molecules.Yoshiaki ShojiNaoki TanakaSho MuranakaNaoki ShigenoHaruka SugiyamaKumiko TakenouchiFatin HajjajTakanori FukushimaNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yoshiaki Shoji Naoki Tanaka Sho Muranaka Naoki Shigeno Haruka Sugiyama Kumiko Takenouchi Fatin Hajjaj Takanori Fukushima Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
description	Coupling reactions to form C–C bonds typically require transition metals. Here the authors report that an organoboron compound can allow sequential alkyne insertion and unusual oxidative deborylation/Csp2 –Csp2 coupling, enabling the transformation of acetylenes into extended π-conjugated molecules.
format	article
author	Yoshiaki Shoji Naoki Tanaka Sho Muranaka Naoki Shigeno Haruka Sugiyama Kumiko Takenouchi Fatin Hajjaj Takanori Fukushima
author_facet	Yoshiaki Shoji Naoki Tanaka Sho Muranaka Naoki Shigeno Haruka Sugiyama Kumiko Takenouchi Fatin Hajjaj Takanori Fukushima
author_sort	Yoshiaki Shoji
title	Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
title_short	Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
title_full	Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
title_fullStr	Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
title_full_unstemmed	Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
title_sort	boron-mediated sequential alkyne insertion and c–c coupling reactions affording extended π-conjugated molecules
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/e1d89bd51ba0497d86ef4fe23d35f06a
work_keys_str_mv	AT yoshiakishoji boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT naokitanaka boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT shomuranaka boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT naokishigeno boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT harukasugiyama boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT kumikotakenouchi boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT fatinhajjaj boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules AT takanorifukushima boronmediatedsequentialalkyneinsertionandcccouplingreactionsaffordingextendedpconjugatedmolecules
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Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules

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