Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions

A stable, earth-abundant, reusable cobalt-based heterogeneous catalyst is developed for the oxidative esterification of alcohols under ambient conditions, featuring broad substrate scope, providing good to excellent product yields. This protocol enables easy recyclability of the catalyst, measured u...

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Main Authors:	Changjian Zhou, Rong Sun, Yuting Zhang, Biao Xiong, Hui Dai, Yong Dai
Format:	article
Language:	EN
Published:	MDPI AG 2021
Subjects:	aerobic oxidation benzyl alcohols heterogeneous cobalt Organic chemistry QD241-441
Online Access:	https://doaj.org/article/e23c63fbd3d0403fa207dce428ca8194
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spelling	oai:doaj.org-article:e23c63fbd3d0403fa207dce428ca81942021-11-25T18:27:16ZCo-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions10.3390/molecules262267921420-3049https://doaj.org/article/e23c63fbd3d0403fa207dce428ca81942021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6792https://doaj.org/toc/1420-3049A stable, earth-abundant, reusable cobalt-based heterogeneous catalyst is developed for the oxidative esterification of alcohols under ambient conditions, featuring broad substrate scope, providing good to excellent product yields. This protocol enables easy recyclability of the catalyst, measured up to five times without significant loss of efficiency. The active sites of Co-N-Si/AC are proposed to be Co-N species.Changjian ZhouRong SunYuting ZhangBiao XiongHui DaiYong DaiMDPI AGarticleaerobic oxidationbenzyl alcoholsheterogeneous cobaltOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6792, p 6792 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	aerobic oxidation benzyl alcohols heterogeneous cobalt Organic chemistry QD241-441
spellingShingle	aerobic oxidation benzyl alcohols heterogeneous cobalt Organic chemistry QD241-441 Changjian Zhou Rong Sun Yuting Zhang Biao Xiong Hui Dai Yong Dai Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
description	A stable, earth-abundant, reusable cobalt-based heterogeneous catalyst is developed for the oxidative esterification of alcohols under ambient conditions, featuring broad substrate scope, providing good to excellent product yields. This protocol enables easy recyclability of the catalyst, measured up to five times without significant loss of efficiency. The active sites of Co-N-Si/AC are proposed to be Co-N species.
format	article
author	Changjian Zhou Rong Sun Yuting Zhang Biao Xiong Hui Dai Yong Dai
author_facet	Changjian Zhou Rong Sun Yuting Zhang Biao Xiong Hui Dai Yong Dai
author_sort	Changjian Zhou
title	Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_short	Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_full	Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_fullStr	Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_full_unstemmed	Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions
title_sort	co-n-si/ac catalyst for aerobic oxidation of benzyl alcohols to esters under mild conditions
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/e23c63fbd3d0403fa207dce428ca8194
work_keys_str_mv	AT changjianzhou consiaccatalystforaerobicoxidationofbenzylalcoholstoestersundermildconditions AT rongsun consiaccatalystforaerobicoxidationofbenzylalcoholstoestersundermildconditions AT yutingzhang consiaccatalystforaerobicoxidationofbenzylalcoholstoestersundermildconditions AT biaoxiong consiaccatalystforaerobicoxidationofbenzylalcoholstoestersundermildconditions AT huidai consiaccatalystforaerobicoxidationofbenzylalcoholstoestersundermildconditions AT yongdai consiaccatalystforaerobicoxidationofbenzylalcoholstoestersundermildconditions
_version_	1718411166189879296

Co-N-Si/AC Catalyst for Aerobic Oxidation of Benzyl Alcohols to Esters under Mild Conditions

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