Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides

Deuterodehalogenation of organic chlorides is a useful strategy to install deuterium atoms at specific positions, however, it has several drawbacks. In this study, the authors report an organophotocatalytic system consisting of an aryl-amine-based photocatalyst and a common disulfide co-catalyst, fo...

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Autores principales:	Yanjun Li, Ziqi Ye, Yu-Mei Lin, Yan Liu, Yumeng Zhang, Lei Gong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e25e2e2e05c1480897c75c3326c4749b
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spelling	oai:doaj.org-article:e25e2e2e05c1480897c75c3326c4749b2021-12-02T15:45:13ZOrganophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides10.1038/s41467-021-23255-02041-1723https://doaj.org/article/e25e2e2e05c1480897c75c3326c4749b2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23255-0https://doaj.org/toc/2041-1723Deuterodehalogenation of organic chlorides is a useful strategy to install deuterium atoms at specific positions, however, it has several drawbacks. In this study, the authors report an organophotocatalytic system consisting of an aryl-amine-based photocatalyst and a common disulfide co-catalyst, for efficient deuteration of a wide range of aryl chlorides, alkyl chlorides and other halides, at room temperature in air.Yanjun LiZiqi YeYu-Mei LinYan LiuYumeng ZhangLei GongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-13 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yanjun Li Ziqi Ye Yu-Mei Lin Yan Liu Yumeng Zhang Lei Gong Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
description	Deuterodehalogenation of organic chlorides is a useful strategy to install deuterium atoms at specific positions, however, it has several drawbacks. In this study, the authors report an organophotocatalytic system consisting of an aryl-amine-based photocatalyst and a common disulfide co-catalyst, for efficient deuteration of a wide range of aryl chlorides, alkyl chlorides and other halides, at room temperature in air.
format	article
author	Yanjun Li Ziqi Ye Yu-Mei Lin Yan Liu Yumeng Zhang Lei Gong
author_facet	Yanjun Li Ziqi Ye Yu-Mei Lin Yan Liu Yumeng Zhang Lei Gong
author_sort	Yanjun Li
title	Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
title_short	Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
title_full	Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
title_fullStr	Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
title_full_unstemmed	Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
title_sort	organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/e25e2e2e05c1480897c75c3326c4749b
work_keys_str_mv	AT yanjunli organophotocatalyticselectivedeuterodehalogenationofaryloralkylchlorides AT ziqiye organophotocatalyticselectivedeuterodehalogenationofaryloralkylchlorides AT yumeilin organophotocatalyticselectivedeuterodehalogenationofaryloralkylchlorides AT yanliu organophotocatalyticselectivedeuterodehalogenationofaryloralkylchlorides AT yumengzhang organophotocatalyticselectivedeuterodehalogenationofaryloralkylchlorides AT leigong organophotocatalyticselectivedeuterodehalogenationofaryloralkylchlorides
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Organophotocatalytic selective deuterodehalogenation of aryl or alkyl chlorides

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