Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S

Anionic redox reactions are gaining interest as a means to optimize capacities of alkaline ion batteries. Here, the authors investigate various charge compensation mechanisms and report S–S dimerization and the formation of electron holes on sulfur in a model sulfide cathode.

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Autores principales: Tian Wang, Guo-Xi Ren, Zulipiya Shadike, Ji-Li Yue, Ming-Hui Cao, Jie-Nan Zhang, Ming-Wei Chen, Xiao-Qing Yang, Seong-Min Bak, Paul Northrup, Pan Liu, Xiao-Song Liu, Zheng-Wen Fu
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/e2a2c114c2aa42ad8e0f8c9673ad2c10
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spelling oai:doaj.org-article:e2a2c114c2aa42ad8e0f8c9673ad2c102021-12-02T16:58:03ZAnionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S10.1038/s41467-019-12310-62041-1723https://doaj.org/article/e2a2c114c2aa42ad8e0f8c9673ad2c102019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12310-6https://doaj.org/toc/2041-1723Anionic redox reactions are gaining interest as a means to optimize capacities of alkaline ion batteries. Here, the authors investigate various charge compensation mechanisms and report S–S dimerization and the formation of electron holes on sulfur in a model sulfide cathode.Tian WangGuo-Xi RenZulipiya ShadikeJi-Li YueMing-Hui CaoJie-Nan ZhangMing-Wei ChenXiao-Qing YangSeong-Min BakPaul NorthrupPan LiuXiao-Song LiuZheng-Wen FuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-12 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Tian Wang
Guo-Xi Ren
Zulipiya Shadike
Ji-Li Yue
Ming-Hui Cao
Jie-Nan Zhang
Ming-Wei Chen
Xiao-Qing Yang
Seong-Min Bak
Paul Northrup
Pan Liu
Xiao-Song Liu
Zheng-Wen Fu
Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S
description Anionic redox reactions are gaining interest as a means to optimize capacities of alkaline ion batteries. Here, the authors investigate various charge compensation mechanisms and report S–S dimerization and the formation of electron holes on sulfur in a model sulfide cathode.
format article
author Tian Wang
Guo-Xi Ren
Zulipiya Shadike
Ji-Li Yue
Ming-Hui Cao
Jie-Nan Zhang
Ming-Wei Chen
Xiao-Qing Yang
Seong-Min Bak
Paul Northrup
Pan Liu
Xiao-Song Liu
Zheng-Wen Fu
author_facet Tian Wang
Guo-Xi Ren
Zulipiya Shadike
Ji-Li Yue
Ming-Hui Cao
Jie-Nan Zhang
Ming-Wei Chen
Xiao-Qing Yang
Seong-Min Bak
Paul Northrup
Pan Liu
Xiao-Song Liu
Zheng-Wen Fu
author_sort Tian Wang
title Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S
title_short Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S
title_full Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S
title_fullStr Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S
title_full_unstemmed Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S
title_sort anionic redox reaction in layered nacr2/3ti1/3s2 through electron holes formation and dimerization of s–s
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/e2a2c114c2aa42ad8e0f8c9673ad2c10
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