Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices

In this work, we systematically studied the deposition, characterization, and crystal structure modeling of ScAlN thin film. Measurements of the piezoelectric device’s relevant material properties, such as crystal structure, crystallographic orientation, and piezoelectric response, were performed to...

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Autores principales: Qiaozhen Zhang, Mingzhu Chen, Huiling Liu, Xiangyong Zhao, Xiaomei Qin, Feifei Wang, Yanxue Tang, Keat Hoe Yeoh, Khian-Hooi Chew, Xiaojuan Sun
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:e3775e311fbb45ed9253c5fda0ec39e12021-11-11T18:00:43ZDeposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices10.3390/ma142164371996-1944https://doaj.org/article/e3775e311fbb45ed9253c5fda0ec39e12021-10-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6437https://doaj.org/toc/1996-1944In this work, we systematically studied the deposition, characterization, and crystal structure modeling of ScAlN thin film. Measurements of the piezoelectric device’s relevant material properties, such as crystal structure, crystallographic orientation, and piezoelectric response, were performed to characterize the Sc<sub>0.29</sub>Al<sub>0.71</sub>N thin film grown using pulsed DC magnetron sputtering. Crystal structure modeling of the ScAlN thin film is proposed and validated, and the structure–property relations are discussed. The investigation results indicated that the sputtered thin film using seed layer technique had a good crystalline quality and a clear grain boundary. In addition, the effective piezoelectric coefficient <i>d</i><sub>33</sub> was up to 12.6 pC/N, and there was no wurtzite-to-rocksalt phase transition under high pressure. These good features demonstrated that the sputtered ScAlN is promising for application in high-coupling piezoelectric devices with high-pressure stability.Qiaozhen ZhangMingzhu ChenHuiling LiuXiangyong ZhaoXiaomei QinFeifei WangYanxue TangKeat Hoe YeohKhian-Hooi ChewXiaojuan SunMDPI AGarticlepiezoelectric thin filmscandium-doped aluminum nitridecrystal structurefirst-principles calculationTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6437, p 6437 (2021)
institution DOAJ
collection DOAJ
language EN
topic piezoelectric thin film
scandium-doped aluminum nitride
crystal structure
first-principles calculation
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle piezoelectric thin film
scandium-doped aluminum nitride
crystal structure
first-principles calculation
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Qiaozhen Zhang
Mingzhu Chen
Huiling Liu
Xiangyong Zhao
Xiaomei Qin
Feifei Wang
Yanxue Tang
Keat Hoe Yeoh
Khian-Hooi Chew
Xiaojuan Sun
Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices
description In this work, we systematically studied the deposition, characterization, and crystal structure modeling of ScAlN thin film. Measurements of the piezoelectric device’s relevant material properties, such as crystal structure, crystallographic orientation, and piezoelectric response, were performed to characterize the Sc<sub>0.29</sub>Al<sub>0.71</sub>N thin film grown using pulsed DC magnetron sputtering. Crystal structure modeling of the ScAlN thin film is proposed and validated, and the structure–property relations are discussed. The investigation results indicated that the sputtered thin film using seed layer technique had a good crystalline quality and a clear grain boundary. In addition, the effective piezoelectric coefficient <i>d</i><sub>33</sub> was up to 12.6 pC/N, and there was no wurtzite-to-rocksalt phase transition under high pressure. These good features demonstrated that the sputtered ScAlN is promising for application in high-coupling piezoelectric devices with high-pressure stability.
format article
author Qiaozhen Zhang
Mingzhu Chen
Huiling Liu
Xiangyong Zhao
Xiaomei Qin
Feifei Wang
Yanxue Tang
Keat Hoe Yeoh
Khian-Hooi Chew
Xiaojuan Sun
author_facet Qiaozhen Zhang
Mingzhu Chen
Huiling Liu
Xiangyong Zhao
Xiaomei Qin
Feifei Wang
Yanxue Tang
Keat Hoe Yeoh
Khian-Hooi Chew
Xiaojuan Sun
author_sort Qiaozhen Zhang
title Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices
title_short Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices
title_full Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices
title_fullStr Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices
title_full_unstemmed Deposition, Characterization, and Modeling of Scandium-Doped Aluminum Nitride Thin Film for Piezoelectric Devices
title_sort deposition, characterization, and modeling of scandium-doped aluminum nitride thin film for piezoelectric devices
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/e3775e311fbb45ed9253c5fda0ec39e1
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AT huilingliu depositioncharacterizationandmodelingofscandiumdopedaluminumnitridethinfilmforpiezoelectricdevices
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AT keathoeyeoh depositioncharacterizationandmodelingofscandiumdopedaluminumnitridethinfilmforpiezoelectricdevices
AT khianhooichew depositioncharacterizationandmodelingofscandiumdopedaluminumnitridethinfilmforpiezoelectricdevices
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