Synthesis and versatile reactivity of scandium phosphinophosphinidene complexes

Rare-earth monometallic phosphinidene complexes have been elusive synthetic targets. Here, the authors describe the synthesis and tunable reactivity of two scandium phosphinophosphinidene complexes containing very unusual Sc-P multiple bonds.

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Detalles Bibliográficos
Autores principales: Bin Feng, Li Xiang, Karl N. McCabe, Laurent Maron, Xuebing Leng, Yaofeng Chen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/e3b5ebb15291481092b30a9885ee145a
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Sumario:Rare-earth monometallic phosphinidene complexes have been elusive synthetic targets. Here, the authors describe the synthesis and tunable reactivity of two scandium phosphinophosphinidene complexes containing very unusual Sc-P multiple bonds.