Gas phase synthesis of [4]-helicene

Helicenes represent key building blocks leading eventually to carbonaceous nanostructures. Here, exploiting [4]-helicene as a benchmark, the authors present a synthetic route to racemic helicenes via a vinylacetylene mediated gas phase chemistry with aryl radicals involving ring annulation.

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Autores principales: Long Zhao, Ralf I. Kaiser, Bo Xu, Utuq Ablikim, Wenchao Lu, Musahid Ahmed, Mikhail M. Evseev, Eugene K. Bashkirov, Valeriy N. Azyazov, Marsel V. Zagidullin, Alexander N. Morozov, A. Hasan Howlader, Stanislaw F. Wnuk, Alexander M. Mebel, Dharati Joshi, Gregory Veber, Felix R. Fischer
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/e40b306592ac46f3bbe375114e8d4a69
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spelling oai:doaj.org-article:e40b306592ac46f3bbe375114e8d4a692021-12-02T15:35:33ZGas phase synthesis of [4]-helicene10.1038/s41467-019-09224-82041-1723https://doaj.org/article/e40b306592ac46f3bbe375114e8d4a692019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09224-8https://doaj.org/toc/2041-1723Helicenes represent key building blocks leading eventually to carbonaceous nanostructures. Here, exploiting [4]-helicene as a benchmark, the authors present a synthetic route to racemic helicenes via a vinylacetylene mediated gas phase chemistry with aryl radicals involving ring annulation.Long ZhaoRalf I. KaiserBo XuUtuq AblikimWenchao LuMusahid AhmedMikhail M. EvseevEugene K. BashkirovValeriy N. AzyazovMarsel V. ZagidullinAlexander N. MorozovA. Hasan HowladerStanislaw F. WnukAlexander M. MebelDharati JoshiGregory VeberFelix R. FischerNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Long Zhao
Ralf I. Kaiser
Bo Xu
Utuq Ablikim
Wenchao Lu
Musahid Ahmed
Mikhail M. Evseev
Eugene K. Bashkirov
Valeriy N. Azyazov
Marsel V. Zagidullin
Alexander N. Morozov
A. Hasan Howlader
Stanislaw F. Wnuk
Alexander M. Mebel
Dharati Joshi
Gregory Veber
Felix R. Fischer
Gas phase synthesis of [4]-helicene
description Helicenes represent key building blocks leading eventually to carbonaceous nanostructures. Here, exploiting [4]-helicene as a benchmark, the authors present a synthetic route to racemic helicenes via a vinylacetylene mediated gas phase chemistry with aryl radicals involving ring annulation.
format article
author Long Zhao
Ralf I. Kaiser
Bo Xu
Utuq Ablikim
Wenchao Lu
Musahid Ahmed
Mikhail M. Evseev
Eugene K. Bashkirov
Valeriy N. Azyazov
Marsel V. Zagidullin
Alexander N. Morozov
A. Hasan Howlader
Stanislaw F. Wnuk
Alexander M. Mebel
Dharati Joshi
Gregory Veber
Felix R. Fischer
author_facet Long Zhao
Ralf I. Kaiser
Bo Xu
Utuq Ablikim
Wenchao Lu
Musahid Ahmed
Mikhail M. Evseev
Eugene K. Bashkirov
Valeriy N. Azyazov
Marsel V. Zagidullin
Alexander N. Morozov
A. Hasan Howlader
Stanislaw F. Wnuk
Alexander M. Mebel
Dharati Joshi
Gregory Veber
Felix R. Fischer
author_sort Long Zhao
title Gas phase synthesis of [4]-helicene
title_short Gas phase synthesis of [4]-helicene
title_full Gas phase synthesis of [4]-helicene
title_fullStr Gas phase synthesis of [4]-helicene
title_full_unstemmed Gas phase synthesis of [4]-helicene
title_sort gas phase synthesis of [4]-helicene
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/e40b306592ac46f3bbe375114e8d4a69
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