Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay

To date the carboacylation of alkenes has been reported only in single- and two-component methodologies. Here, the authors report a three-component nickel-catalyzed carboacylation of olefins which enables the rapid construction of ketones with high levels of complexity and diversity.

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Autores principales:	Xian Zhao, Hai-Yong Tu, Lei Guo, Shengqing Zhu, Feng-Ling Qing, Lingling Chu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e47c110e45244dd8aba2aefe8589ec40
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spelling	oai:doaj.org-article:e47c110e45244dd8aba2aefe8589ec402021-12-02T15:34:41ZIntermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay10.1038/s41467-018-05951-62041-1723https://doaj.org/article/e47c110e45244dd8aba2aefe8589ec402018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05951-6https://doaj.org/toc/2041-1723To date the carboacylation of alkenes has been reported only in single- and two-component methodologies. Here, the authors report a three-component nickel-catalyzed carboacylation of olefins which enables the rapid construction of ketones with high levels of complexity and diversity.Xian ZhaoHai-Yong TuLei GuoShengqing ZhuFeng-Ling QingLingling ChuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xian Zhao Hai-Yong Tu Lei Guo Shengqing Zhu Feng-Ling Qing Lingling Chu Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
description	To date the carboacylation of alkenes has been reported only in single- and two-component methodologies. Here, the authors report a three-component nickel-catalyzed carboacylation of olefins which enables the rapid construction of ketones with high levels of complexity and diversity.
format	article
author	Xian Zhao Hai-Yong Tu Lei Guo Shengqing Zhu Feng-Ling Qing Lingling Chu
author_facet	Xian Zhao Hai-Yong Tu Lei Guo Shengqing Zhu Feng-Ling Qing Lingling Chu
author_sort	Xian Zhao
title	Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
title_short	Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
title_full	Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
title_fullStr	Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
title_full_unstemmed	Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
title_sort	intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/e47c110e45244dd8aba2aefe8589ec40
work_keys_str_mv	AT xianzhao intermolecularselectivecarboacylationofalkenesvianickelcatalyzedreductiveradicalrelay AT haiyongtu intermolecularselectivecarboacylationofalkenesvianickelcatalyzedreductiveradicalrelay AT leiguo intermolecularselectivecarboacylationofalkenesvianickelcatalyzedreductiveradicalrelay AT shengqingzhu intermolecularselectivecarboacylationofalkenesvianickelcatalyzedreductiveradicalrelay AT fenglingqing intermolecularselectivecarboacylationofalkenesvianickelcatalyzedreductiveradicalrelay AT linglingchu intermolecularselectivecarboacylationofalkenesvianickelcatalyzedreductiveradicalrelay
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Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay

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