Cavity frequency-dependent theory for vibrational polariton chemistry

Vibrational strong coupling controls the ground-state reactivity of molecules in optical cavities, but the underlying theory is still elusive. The authors analyze a molecular system coupled to a cavity mode and find that the reaction rate is suppressed for a particular cavity frequency, related to t...

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Autores principales: Xinyang Li, Arkajit Mandal, Pengfei Huo
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/e4a8c45296954a5cb7fa8a646ce28f23
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