Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents
The electrochromic properties of monobenzyl-viologen (MBV) and dibenzyl-viologen (DBV) in chloride-ethylene glycol deep eutectic solvents (DES) are studied by cyclic voltammetry and in situ UV-vis spectroscopy. The results show that redox reactions of both viologens between bleached and colored stat...
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Academic Journals Center of Shanghai Normal University
2021
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oai:doaj.org-article:e4e0fc3b416348668bb326b7e8f0db8e2021-11-12T03:34:00ZElectrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents1000-513710.3969/J.ISSN.1000-5137.2021.05.010https://doaj.org/article/e4e0fc3b416348668bb326b7e8f0db8e2021-10-01T00:00:00Zhttp://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/view_abstract.aspx?file_no=20210510https://doaj.org/toc/1000-5137The electrochromic properties of monobenzyl-viologen (MBV) and dibenzyl-viologen (DBV) in chloride-ethylene glycol deep eutectic solvents (DES) are studied by cyclic voltammetry and in situ UV-vis spectroscopy. The results show that redox reactions of both viologens between bleached and colored state are reversible. The DBV showed a blue colored state and the MBV showed a magenta colored state, respectively. According to the CIE colorimetric data, with a solution containing the mixture of DBV and MBV in a molar ratio of 1:2, multi-colored states from colorless→blue→red-violet under various voltages were observed.TAO KaixinLU ShengnanWANG RongCAO XiaoweiAcademic Journals Center of Shanghai Normal Universityarticleelectrochromicdibenzyl-viologen(dbv)monobenzyl-viologen(mbv)deep eutectic solvent(des)Science (General)Q1-390ENZHJournal of Shanghai Normal University (Natural Sciences), Vol 50, Iss 5, Pp 597-603 (2021) |
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electrochromic dibenzyl-viologen(dbv) monobenzyl-viologen(mbv) deep eutectic solvent(des) Science (General) Q1-390 |
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electrochromic dibenzyl-viologen(dbv) monobenzyl-viologen(mbv) deep eutectic solvent(des) Science (General) Q1-390 TAO Kaixin LU Shengnan WANG Rong CAO Xiaowei Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
description |
The electrochromic properties of monobenzyl-viologen (MBV) and dibenzyl-viologen (DBV) in chloride-ethylene glycol deep eutectic solvents (DES) are studied by cyclic voltammetry and in situ UV-vis spectroscopy. The results show that redox reactions of both viologens between bleached and colored state are reversible. The DBV showed a blue colored state and the MBV showed a magenta colored state, respectively. According to the CIE colorimetric data, with a solution containing the mixture of DBV and MBV in a molar ratio of 1:2, multi-colored states from colorless→blue→red-violet under various voltages were observed. |
format |
article |
author |
TAO Kaixin LU Shengnan WANG Rong CAO Xiaowei |
author_facet |
TAO Kaixin LU Shengnan WANG Rong CAO Xiaowei |
author_sort |
TAO Kaixin |
title |
Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
title_short |
Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
title_full |
Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
title_fullStr |
Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
title_full_unstemmed |
Electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
title_sort |
electrochromic behavior of mono and dibenzyl substituted viologens in deep eutectic solvents |
publisher |
Academic Journals Center of Shanghai Normal University |
publishDate |
2021 |
url |
https://doaj.org/article/e4e0fc3b416348668bb326b7e8f0db8e |
work_keys_str_mv |
AT taokaixin electrochromicbehaviorofmonoanddibenzylsubstitutedviologensindeepeutecticsolvents AT lushengnan electrochromicbehaviorofmonoanddibenzylsubstitutedviologensindeepeutecticsolvents AT wangrong electrochromicbehaviorofmonoanddibenzylsubstitutedviologensindeepeutecticsolvents AT caoxiaowei electrochromicbehaviorofmonoanddibenzylsubstitutedviologensindeepeutecticsolvents |
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