A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
Functionalization of C-H bonds typically requires harsh reagents or metal catalysts. Here the authors report a metal-free C-H sulfenylation/rearrangement to form C-S and S=N bonds under simple, biocompatible conditions, and apply this to the synthesis of fluorogenic phospholipid vesicles.
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Nature Portfolio
2017
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oai:doaj.org-article:e57c5fc7d52645ee838742b35e4dd45c2021-12-02T17:06:05ZA bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis10.1038/ncomms159122041-1723https://doaj.org/article/e57c5fc7d52645ee838742b35e4dd45c2017-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms15912https://doaj.org/toc/2041-1723Functionalization of C-H bonds typically requires harsh reagents or metal catalysts. Here the authors report a metal-free C-H sulfenylation/rearrangement to form C-S and S=N bonds under simple, biocompatible conditions, and apply this to the synthesis of fluorogenic phospholipid vesicles.Feng XiongLiang LuTian-Yu SunQian WuDingyuan YanYing ChenXinhao ZhangWei WeiYi LuWei-Yin SunJie Jack LiJing ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Feng Xiong Liang Lu Tian-Yu Sun Qian Wu Dingyuan Yan Ying Chen Xinhao Zhang Wei Wei Yi Lu Wei-Yin Sun Jie Jack Li Jing Zhao A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
description |
Functionalization of C-H bonds typically requires harsh reagents or metal catalysts. Here the authors report a metal-free C-H sulfenylation/rearrangement to form C-S and S=N bonds under simple, biocompatible conditions, and apply this to the synthesis of fluorogenic phospholipid vesicles. |
format |
article |
author |
Feng Xiong Liang Lu Tian-Yu Sun Qian Wu Dingyuan Yan Ying Chen Xinhao Zhang Wei Wei Yi Lu Wei-Yin Sun Jie Jack Li Jing Zhao |
author_facet |
Feng Xiong Liang Lu Tian-Yu Sun Qian Wu Dingyuan Yan Ying Chen Xinhao Zhang Wei Wei Yi Lu Wei-Yin Sun Jie Jack Li Jing Zhao |
author_sort |
Feng Xiong |
title |
A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
title_short |
A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
title_full |
A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
title_fullStr |
A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
title_full_unstemmed |
A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
title_sort |
bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/e57c5fc7d52645ee838742b35e4dd45c |
work_keys_str_mv |
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