A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis

Functionalization of C-H bonds typically requires harsh reagents or metal catalysts. Here the authors report a metal-free C-H sulfenylation/rearrangement to form C-S and S=N bonds under simple, biocompatible conditions, and apply this to the synthesis of fluorogenic phospholipid vesicles.

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Autores principales: Feng Xiong, Liang Lu, Tian-Yu Sun, Qian Wu, Dingyuan Yan, Ying Chen, Xinhao Zhang, Wei Wei, Yi Lu, Wei-Yin Sun, Jie Jack Li, Jing Zhao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/e57c5fc7d52645ee838742b35e4dd45c
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spelling oai:doaj.org-article:e57c5fc7d52645ee838742b35e4dd45c2021-12-02T17:06:05ZA bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis10.1038/ncomms159122041-1723https://doaj.org/article/e57c5fc7d52645ee838742b35e4dd45c2017-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms15912https://doaj.org/toc/2041-1723Functionalization of C-H bonds typically requires harsh reagents or metal catalysts. Here the authors report a metal-free C-H sulfenylation/rearrangement to form C-S and S=N bonds under simple, biocompatible conditions, and apply this to the synthesis of fluorogenic phospholipid vesicles.Feng XiongLiang LuTian-Yu SunQian WuDingyuan YanYing ChenXinhao ZhangWei WeiYi LuWei-Yin SunJie Jack LiJing ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Feng Xiong
Liang Lu
Tian-Yu Sun
Qian Wu
Dingyuan Yan
Ying Chen
Xinhao Zhang
Wei Wei
Yi Lu
Wei-Yin Sun
Jie Jack Li
Jing Zhao
A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
description Functionalization of C-H bonds typically requires harsh reagents or metal catalysts. Here the authors report a metal-free C-H sulfenylation/rearrangement to form C-S and S=N bonds under simple, biocompatible conditions, and apply this to the synthesis of fluorogenic phospholipid vesicles.
format article
author Feng Xiong
Liang Lu
Tian-Yu Sun
Qian Wu
Dingyuan Yan
Ying Chen
Xinhao Zhang
Wei Wei
Yi Lu
Wei-Yin Sun
Jie Jack Li
Jing Zhao
author_facet Feng Xiong
Liang Lu
Tian-Yu Sun
Qian Wu
Dingyuan Yan
Ying Chen
Xinhao Zhang
Wei Wei
Yi Lu
Wei-Yin Sun
Jie Jack Li
Jing Zhao
author_sort Feng Xiong
title A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
title_short A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
title_full A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
title_fullStr A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
title_full_unstemmed A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
title_sort bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/e57c5fc7d52645ee838742b35e4dd45c
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