Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules

Electrochemical oxidative C–C bond cleavage and functionalization are rarely developed due to the inertness and weak electronic bias of C–C bonds. In this study, the authors report the electrochemical C–C bond cleavage and 1,3-difluorination, 1,3-oxyfluorination and 1,3-dioxygenation of arylcyclopro...

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Autores principales:	Pan Peng, Xingxiu Yan, Ke Zhang, Zhao Liu, Li Zeng, Yixuan Chen, Heng Zhang, Aiwen Lei
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e5ab8ed784c04acdb07230676828ba79
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spelling	oai:doaj.org-article:e5ab8ed784c04acdb07230676828ba792021-12-02T14:42:19ZElectrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules10.1038/s41467-021-23401-82041-1723https://doaj.org/article/e5ab8ed784c04acdb07230676828ba792021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23401-8https://doaj.org/toc/2041-1723Electrochemical oxidative C–C bond cleavage and functionalization are rarely developed due to the inertness and weak electronic bias of C–C bonds. In this study, the authors report the electrochemical C–C bond cleavage and 1,3-difluorination, 1,3-oxyfluorination and 1,3-dioxygenation of arylcyclopropanes under catalyst-free and external-oxidant-free conditions.Pan PengXingxiu YanKe ZhangZhao LiuLi ZengYixuan ChenHeng ZhangAiwen LeiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Pan Peng Xingxiu Yan Ke Zhang Zhao Liu Li Zeng Yixuan Chen Heng Zhang Aiwen Lei Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
description	Electrochemical oxidative C–C bond cleavage and functionalization are rarely developed due to the inertness and weak electronic bias of C–C bonds. In this study, the authors report the electrochemical C–C bond cleavage and 1,3-difluorination, 1,3-oxyfluorination and 1,3-dioxygenation of arylcyclopropanes under catalyst-free and external-oxidant-free conditions.
format	article
author	Pan Peng Xingxiu Yan Ke Zhang Zhao Liu Li Zeng Yixuan Chen Heng Zhang Aiwen Lei
author_facet	Pan Peng Xingxiu Yan Ke Zhang Zhao Liu Li Zeng Yixuan Chen Heng Zhang Aiwen Lei
author_sort	Pan Peng
title	Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
title_short	Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
title_full	Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
title_fullStr	Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
title_full_unstemmed	Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
title_sort	electrochemical c−c bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/e5ab8ed784c04acdb07230676828ba79
work_keys_str_mv	AT panpeng electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT xingxiuyan electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT kezhang electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT zhaoliu electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT lizeng electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT yixuanchen electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT hengzhang electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules AT aiwenlei electrochemicalccbondcleavageofcyclopropanestowardsthesynthesisof13difunctionalizedmolecules
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Electrochemical C−C bond cleavage of cyclopropanes towards the synthesis of 1,3-difunctionalized molecules

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