Hydrogen bonds to Au atoms in coordinated gold clusters

Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactio...

Description complète

Enregistré dans:
Détails bibliographiques
Auteurs principaux: Md. Abu Bakar, Mizuho Sugiuchi, Mitsuhiro Iwasaki, Yukatsu Shichibu, Katsuaki Konishi
Format: article
Langue:EN
Publié: Nature Portfolio 2017
Sujets:
Q
Accès en ligne:https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d
Tags: Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
id oai:doaj.org-article:e5d033d6df1c4ade9c75107ebb9e080d
record_format dspace
spelling oai:doaj.org-article:e5d033d6df1c4ade9c75107ebb9e080d2021-12-02T14:40:47ZHydrogen bonds to Au atoms in coordinated gold clusters10.1038/s41467-017-00720-32041-1723https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00720-3https://doaj.org/toc/2041-1723Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactions may play a role in gold cluster catalysis.Md. Abu BakarMizuho SugiuchiMitsuhiro IwasakiYukatsu ShichibuKatsuaki KonishiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Md. Abu Bakar
Mizuho Sugiuchi
Mitsuhiro Iwasaki
Yukatsu Shichibu
Katsuaki Konishi
Hydrogen bonds to Au atoms in coordinated gold clusters
description Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactions may play a role in gold cluster catalysis.
format article
author Md. Abu Bakar
Mizuho Sugiuchi
Mitsuhiro Iwasaki
Yukatsu Shichibu
Katsuaki Konishi
author_facet Md. Abu Bakar
Mizuho Sugiuchi
Mitsuhiro Iwasaki
Yukatsu Shichibu
Katsuaki Konishi
author_sort Md. Abu Bakar
title Hydrogen bonds to Au atoms in coordinated gold clusters
title_short Hydrogen bonds to Au atoms in coordinated gold clusters
title_full Hydrogen bonds to Au atoms in coordinated gold clusters
title_fullStr Hydrogen bonds to Au atoms in coordinated gold clusters
title_full_unstemmed Hydrogen bonds to Au atoms in coordinated gold clusters
title_sort hydrogen bonds to au atoms in coordinated gold clusters
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d
work_keys_str_mv AT mdabubakar hydrogenbondstoauatomsincoordinatedgoldclusters
AT mizuhosugiuchi hydrogenbondstoauatomsincoordinatedgoldclusters
AT mitsuhiroiwasaki hydrogenbondstoauatomsincoordinatedgoldclusters
AT yukatsushichibu hydrogenbondstoauatomsincoordinatedgoldclusters
AT katsuakikonishi hydrogenbondstoauatomsincoordinatedgoldclusters
_version_ 1718390142876516352