Hydrogen bonds to Au atoms in coordinated gold clusters
Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactio...
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Nature Portfolio
2017
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oai:doaj.org-article:e5d033d6df1c4ade9c75107ebb9e080d2021-12-02T14:40:47ZHydrogen bonds to Au atoms in coordinated gold clusters10.1038/s41467-017-00720-32041-1723https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00720-3https://doaj.org/toc/2041-1723Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactions may play a role in gold cluster catalysis.Md. Abu BakarMizuho SugiuchiMitsuhiro IwasakiYukatsu ShichibuKatsuaki KonishiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Md. Abu Bakar Mizuho Sugiuchi Mitsuhiro Iwasaki Yukatsu Shichibu Katsuaki Konishi Hydrogen bonds to Au atoms in coordinated gold clusters |
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Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactions may play a role in gold cluster catalysis. |
format |
article |
author |
Md. Abu Bakar Mizuho Sugiuchi Mitsuhiro Iwasaki Yukatsu Shichibu Katsuaki Konishi |
author_facet |
Md. Abu Bakar Mizuho Sugiuchi Mitsuhiro Iwasaki Yukatsu Shichibu Katsuaki Konishi |
author_sort |
Md. Abu Bakar |
title |
Hydrogen bonds to Au atoms in coordinated gold clusters |
title_short |
Hydrogen bonds to Au atoms in coordinated gold clusters |
title_full |
Hydrogen bonds to Au atoms in coordinated gold clusters |
title_fullStr |
Hydrogen bonds to Au atoms in coordinated gold clusters |
title_full_unstemmed |
Hydrogen bonds to Au atoms in coordinated gold clusters |
title_sort |
hydrogen bonds to au atoms in coordinated gold clusters |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d |
work_keys_str_mv |
AT mdabubakar hydrogenbondstoauatomsincoordinatedgoldclusters AT mizuhosugiuchi hydrogenbondstoauatomsincoordinatedgoldclusters AT mitsuhiroiwasaki hydrogenbondstoauatomsincoordinatedgoldclusters AT yukatsushichibu hydrogenbondstoauatomsincoordinatedgoldclusters AT katsuakikonishi hydrogenbondstoauatomsincoordinatedgoldclusters |
_version_ |
1718390142876516352 |