Hydrogen bonds to Au atoms in coordinated gold clusters

Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactio...

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Main Authors:	Md. Abu Bakar, Mizuho Sugiuchi, Mitsuhiro Iwasaki, Yukatsu Shichibu, Katsuaki Konishi
Format:	article
Language:	EN
Published:	Nature Portfolio 2017
Subjects:	Science Q
Online Access:	https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d
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spelling	oai:doaj.org-article:e5d033d6df1c4ade9c75107ebb9e080d2021-12-02T14:40:47ZHydrogen bonds to Au atoms in coordinated gold clusters10.1038/s41467-017-00720-32041-1723https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00720-3https://doaj.org/toc/2041-1723Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactions may play a role in gold cluster catalysis.Md. Abu BakarMizuho SugiuchiMitsuhiro IwasakiYukatsu ShichibuKatsuaki KonishiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Md. Abu Bakar Mizuho Sugiuchi Mitsuhiro Iwasaki Yukatsu Shichibu Katsuaki Konishi Hydrogen bonds to Au atoms in coordinated gold clusters
description	Many transition metals can form hydrogen bonds to organic species, but experimental evidence for Au is still lacking. Here, the authors obtain crystallographic and NMR spectroscopic evidence of hydrogen bonding between C-H groups and Au atoms of gold clusters, suggesting that non-covalent interactions may play a role in gold cluster catalysis.
format	article
author	Md. Abu Bakar Mizuho Sugiuchi Mitsuhiro Iwasaki Yukatsu Shichibu Katsuaki Konishi
author_facet	Md. Abu Bakar Mizuho Sugiuchi Mitsuhiro Iwasaki Yukatsu Shichibu Katsuaki Konishi
author_sort	Md. Abu Bakar
title	Hydrogen bonds to Au atoms in coordinated gold clusters
title_short	Hydrogen bonds to Au atoms in coordinated gold clusters
title_full	Hydrogen bonds to Au atoms in coordinated gold clusters
title_fullStr	Hydrogen bonds to Au atoms in coordinated gold clusters
title_full_unstemmed	Hydrogen bonds to Au atoms in coordinated gold clusters
title_sort	hydrogen bonds to au atoms in coordinated gold clusters
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/e5d033d6df1c4ade9c75107ebb9e080d
work_keys_str_mv	AT mdabubakar hydrogenbondstoauatomsincoordinatedgoldclusters AT mizuhosugiuchi hydrogenbondstoauatomsincoordinatedgoldclusters AT mitsuhiroiwasaki hydrogenbondstoauatomsincoordinatedgoldclusters AT yukatsushichibu hydrogenbondstoauatomsincoordinatedgoldclusters AT katsuakikonishi hydrogenbondstoauatomsincoordinatedgoldclusters
_version_	1718390142876516352

Hydrogen bonds to Au atoms in coordinated gold clusters

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